Exolit® AP 462

Exolit® AP 462 is a product based on ammonium polyphosphate. The crystal modification is phase II. It is manufactured from ammonium polyphosphate by micro-encapsulation with melamine resin according to Clariant’s own method. Exolit® AP 462 is a fine-particle white powder with very low solubility in water, even at elevated temperatures. It is completely insoluble in organic solvents. The product is non-hygroscopic and non-flammable.

Principal: Clariant Additives

Functions: Flame Retardant, Flame Retardant

Chemical Family: Ammonium Salts, Polyphosphates

End Uses: Casting Resin, Intumescent Coating, Paper, Polyurethane Foams

Compatible Polymers & Resins: Epoxies (EP), Polyesters

Features: Low Viscosity, Low Water Solubility

Labeling Claims: Non-Flammable

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Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Chemical Name
Function
Flame Retardant
Industrial Additives Functions
Molecular Formula
(NH₄PO₃)ₙ (n - min.1000)
Product Code
MITM02887
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

CASE Ingredients Features
Labeling Claims
Product Benefits
  • Extremely low water solubility
  • Completely insoluble in organic solvents, non-hygroscopic and non-flammable
  • Even lower viscosity in aqueous suspension, lower heat stability in the temperature range > 300 °C and improved powder flowability in comparison to Exolit® AP 422 Can be used for all applications where ammonium polyphosphate is suitable
  • Can be used advantageously in intumescent coatings where the ammonium polyphosphate is required to have extremely low water solubility and where lower heat stability at temperatures above 300 °C contributes to more rapid foaming of the coating
  • Particularly suitable as an ”acid donor” for intumescent coatings thanks to its low water solubility. Steel structures coated with intumescent paints can meet the requirements of fire resistance classes specified in EN, DIN, BS, ASTM and others. The application of Exolit® AP 462 based intumescent coatings on wood or plastics enables these materials to qualify for Building Material Class B (DIN EN 13501-1)
  • Imparts a good flame-retardant effect to adhesives and sealants when it is incorporated into the base formulation at the rate of 10 - 20%
  • Suitable non-halogenated flame retardant for polyurethane foams
  • Excellent flame-retardant effect in cellulose-containing materials such as paper and wood products
  • With chipboard products, the B classification according to DIN EN 13501-1 can be achieved by adding 15 - 20%
  • Casting resins based on epoxy resins or unsaturated polyester resins achieve the classification UL94-V0
  • Non-halogenated flame retardant with favorable environmental and health profile

Applications & Uses

Application Area
Coating End Applications
Compatible Polymers & Resins
Compatible Substrates & Surfaces
Industrial Additives End Use
Product Applications
  • Exolit® AP 462 can be used for all applications ammonium polyphosphate is suitable for. In cases where a specific phosphorus content is required to obtain the desired effect, the lower phosphorus content of Exolit® AP 462 should be compensated by increasing the amount of product added.
  • Exolit® AP 462 can be used advantageously in intumescent coatings where the ammonium polyphosphate is required to have extremely low water solubility and where lower heat stability at temperatures above 300 °C contributes to more rapid foaming of the coating.
  • Intumescent coatings
  • On account of its low water solubility, Exolit AP 462 is particularly suitable as an ”acid donor” for intumescent coatings. Other essential components of intumescent systems include a binder, a carbon donor (e.g. pentaerythritol) and a blowing agent (e.g. melamine).
  • On exposure to flame, the intumescent coatings form a carbonaceous foam which effectively shields the underlying material from temperature increases.
  • Steel structures coated with intumescent paints can meet the requirements of fire resistance classes specified in EN, DIN, BS, ASTM and others.
  • The application of Exolit AP 462 based intumescent coatings on wood or plastics enables these materials to qualify for Building Material Class B (DIN EN 13501-1).
  • Exolit AP 462 imparts a good flame-retardant effect to adhesives and sealants when it is incorporated into the base formulation at the rate of 10 - 20 %.
  • Polyurethane foams
  • Exolit AP 462 is a suitable non-halogenated flame retardant for polyurethane foams. If handling of Exolit AP 462 as a solid is not possible we recommend the dosage of the flame retardant by preparing an Exolit AP 462/polyol-suspension. Because of the low acid number of Exolit AP 462 it is also possible to incorporate this flame retardant in an
  • Exolit AP 462/isocyanate suspension. To prevent the solid from settling the Exolit AP 462 suspensions should be stirred or circulated by pump.
  • Other applications
  • Exolit AP 462 has an excellent flame-retardant effect in cellulose-containing materials such as paper and wood products. With chipboard products the B classification according to DIN EN 13501-1 can be achieved by adding 15 - 20 % Exolit AP 462. Casting resins based on epoxy resins or unsaturated polyester resins achieve the classification UL94- V0 with Exolit AP 462.

Properties

Color (Properties)
Physical Form

Packaging & Availability

Packaging Type
Packaging Information
  • Delivery form: White powder
  • Packaging: Exolit® AP 462 is packed in 40 x 25 kg-paper bags (polyethylene inliner) net per 1.000 kg-pallet, shrink-wrapped. Exolit AP 462 can also be supplied in a variety of big bags, shrink-wrapped.

Storage & Handling

Storage and Shelf Life Conditions
  • Minimum shelf life is 12 months from the date of shipping when stored according to the recommended conditions.

Other

Acid Number
max. 0.5 mg KOH/g
Appearance (SDS)
Solid
Bulk Density
0.9 g/cm³
Bulk Density (SDS)
900.0 kg/m³
Burning Number (SDS)
1.0
Color (SDS)
White
Decomposition Temperature (SDS)
min. 527.0 °F
Decomposition Temperature (SDS)
min. 527.0 °F
Density
1.9 g/cm³
Density (SDS)
1.9 g/cm³
Dust Explosion Class (SDS)
Not capable of dust explosion
Explosive Nature (SDS)
Not explosive
Item Number
Moisture Content
max. 1.0 %(W/W)
Nitrogen Content
15.0-17.0 %(W/W)
Other Hazards
No additional hazards are known except those derived from the labelling.
Oxidizing Properties (SDS)
Not oxidising
Particle Size
20.0 µm
Phosphorus Content
29.0-31.0 %(W/W)
Principal
Shelf Life
12.0 mo
Sieve Fractionation (Through)
max. 0.2 %(W/W)
Solubility In Water (SDS)
max. 0.4 g/L
Solubility in Water
max. 0.04 %(W/W)
Vapor Pressure (SDS)
max. 1.0 mbar
Viscosity
max. 20.0 mPa.s
Viscosity (SDS)
max. 20.0 mPa.s
pH
6.5-8.5
pH (SDS)
7.0
Chemical Properties
ValueUnitsTest Method / Conditions
Acid Numbermax. 0.5 mg KOH/gmg KOH/g
Nitrogen Content15.0-17.0 %(W/W)%(W/W)Elemental Analysis
pH6.5-8.5-
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life12.0 momo
Physical Properties
ValueUnitsTest Method / Conditions
Bulk Density0.9 g/cm³g/cm³
Density1.9 g/cm³g/cm³At 25°C
Moisture Contentmax. 1.0 %(W/W)%(W/W)Thermo-Gravimetric Analysis at 130°C
Particle Size20.0 µmµmD50
Sieve Fractionation (Through)max. 0.2 %(W/W)%(W/W)-100 Μm
Solubility in Watermax. 0.04 %(W/W)%(W/W)
Viscositymax. 20.0 mPa.smPa.sat 25°C, 10% aqueous solution
Material Composition
ValueUnitsTest Method / Conditions
Phosphorus Content29.0-31.0 %(W/W)%(W/W)Photometer after oxidizing dissolution
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Bulk Density (SDS)900.0 kg/m³kg/m³at 20°C
Burning Number (SDS)1.0-Does not catch fire
Decomposition Temperature (SDS)min. 527.0 °F°F
Decomposition Temperature (SDS)min. 527.0 °F°FDifferential Thermal Analysis start of decomposition
Density (SDS)1.9 g/cm³g/cm³at 25°C
Solubility In Water (SDS)max. 0.4 g/Lg/Lat 25°C
Vapor Pressure (SDS)max. 1.0 mbarmbarAt 20°C
Viscosity (SDS)max. 20.0 mPa.smPa.sat 25°C, 100 g/l in water
pH (SDS)7.0-at 25°C