RHOPLEX® E-32NP

RHOPLEX® E-32 NP are self-crosslinking polymers which offer excellent strength and solvent resistance to both durable and disposable nonwovens. It performs well with synthetic fibers, cellulosics and blends and can be used on conventional bonding, drying and curing lines. This water-based emulsion is hydrophilic, impart an intermediate hand and are suitable where maximum durability to washing or dry cleaning is required.

Principal: Dow Adhesives

Chemical Family: Acrylics & Acrylates

Functions: Binder & Resin

End Uses: Nonwovens

Features: Dry Cleaning Resistance, High Durability, High Durability, High Strength, High Tensile Strength, Hydrophilic, Solvent Resistance, Solvent Resistance, Wash Resistance

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Enhanced TDS

Identification & Functionality

Features & Benefits

CASE Ingredients Features
Industrial Additives Features
Product Benefits

• Excellent solvent resistance to some solvents used in dry cleaning or industrial wipes

• Excellent durability to washing and dry cleaning
• Excellent wet and dry tensile strength
• Intermediate hand

Product Features

Table below shows that webs bonded with RHOPLEX® E-32 NP have excellent tensile strength under both dry and wet conditions. Both the carded rayon and polyester webs bonded with these binders survived 10 wash cycles or 5 commercial dry cleaning cycles, demonstrating their excellent durability. Table also compares the hand and drape-flex of these emulsions.  All webs were bonded, dried, cured, and tested under laboratory conditions.

Rayon Webs
Tensile, g/inch width (MD/CMD)
Polyester Webs
Tensile, g/inch width (MD/CMD)
Dry 3000/500 Dry 4300/1100
Water wet 1100/300 Water wet 2700/600
Isopropanol wet 2500/300 Isopropanol wet 1700/400
Handᵇ 3.1 Handᵇ 2.3
Drape-Flexᶜ, mm 74 Drape-Flexᶜ, mm 110

 

Table  – Properties of Carded Nonwoven Websᵃ Bonded with RHOPLEX® E-32 NP Emulsion.

Note - ᵃ - Prebonded with 0.25% polyvinyl alcohol; fiber/binder

           ᵇ - Average rating of 7 panelists; lower numbers = softer hand.

           ᶜ - Length of unsupported sample strips (MD) required for a 41.5 overhang.

           

 

 

 

Applications & Uses

Industrial Additives End Use
Markets
Applications
Product Applications

RHOPLEX® E-32 NP is a versatile emulsion, can be used in various applications including interlinings, wet wipes and home furnishings. It is especially suitable for applications where the bonded web will be subjected to some solvents such as those used in dry cleaning or industrial wipes. In addition, RHOPLEX® E-32 NP Emulsion will be able to withstand long term exposure to lotions such as those found in premoistened towelettes.

Formulation Information
  • Crosslinking - As self-crosslinking acrylic emulsions, RHOPLEX® E-32 NP Emulsion does not require the addition of an external crosslinking agent for durability or wet strength. However where maximum solvent resistance is required, a thermosetting resin such as methylated melamine formaldehyde resin at 0.5 to 3% solids on emulsion solids can be used.
  • Catalyst - Acid catalysts such as ammonium nitrate and oxalic acid can be used to accelerate the cure of RHOPLEX® E-32 NP Emulsion  where curing capacity is limited. The following levels of catalyst are recommended
Catalyst Concentration
(solids on emulsion solids)
Comment
Oxalic acid 0.5% Add as a 10% solution
Ammonium nitrate 1.5% Add as a 25% solution

 

  • Surfactant - A nonionic surfactant is recommended in the formulation to achieve better wetting of the fibers. This surfactant should be used at a starting level of 0.5% solids on polymer solids and diluted with at least 3 times its weight of warm water before being added to the formulation. An anionic surfactant should be used where rewetting properties in the end product are desirable. The same solids level and predilution can be used.
  • Defoamer - A general purpose defoamer is recommended with RHOPLEX® E- 32 NP Emulsion at a starting level of 0.05 to 0.1% (product as supplied) on the total weight of the formulation. Prior to use, any defoamer should be pre-emulsified with at least an equal weight of warm water and added to the emulsion, under agitation, before other compounding agents.
  • pH - To maximize emulsion shear stability, the pH of the bath should be adjusted to 8.0 to 8.5 with a volatile base such as ammonium hydroxide.

Properties

Physical Form

Regulatory & Compliance

Certifications & Compliance
Contains any chemicals listed on Prop 65 (including impurities, residues, catalysts, monomers, and by-products and excluding heavy metals)?

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000005
Principal

Other

Appearance
Milky-white self-crossing acrylic liquid
Color (SDS)
White
Item Number
Odor (SDS)
Acrylic like
Other Hazards
No data available
USA/DOT UN Number
Not Applicable
Chemical Properties
ValueUnitsTest Method / Conditions
pH2.5-
Physical Properties
ValueUnitsTest Method / Conditions
Density8.8lb/galAt 25°C
Glass Transition Temperature (Tg)5.0°CDifferential Scanning Calorimetry
Viscosity50.0cPsBrookfield Viscometer at 25°C
Material Composition
ValueUnitsTest Method / Conditions
Solid Content46.0%
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Boiling Point (SDS)100.0°C
Evaporation Rate (SDS)max. 1.0%
Melting Point (SDS)0.0°C
Relative Vapor Density (SDS)max. 1.0-Air = 1
Specific Gravity (SDS)1.0-1.2-Water = 1
Vapor Pressure (SDS)17.0mm Hgat 20°C
Viscosity (SDS)max. 100.0mPa.s
Volatile Content (SDS)53.5-54.5%
pH (SDS)2.1-3.1-