CRAYVALLAC® MT

Principal: Arkema Rheology and Specialty Additives Group

Functions: Rheology Modifier

Chemical Family: Castor Oil Derivatives

End Uses: Solventborne Coating, Solventless & High Solids Coating

Physical Form: Powder, Solid

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Identification & Functionality

CASE Ingredients Functions
Chemical Family
Chemical Name
Country of Origin
Function
Rheology Modifier
Product Code
MITM01575
Technologies
Product Families

Features & Benefits

CASE Ingredients Features
Product Benefits
  • CRAYVALLAC® MT is a micronised amide modified hydrogenated castor oil rheology modifier for solvent-based and solvent-free coatings.
  • CRAYVALLAC® MT is suited to coating systems based on aliphatic hydrocarbons, aromatic hydrocarbons and aromatic hydrocarbon/alcohol blends.
  • Compared to the most basic hydrogenated castor oil based rheology modifiers, CRAYVALLAC® MT is more tolerant to stronger solvents.
  • The result of this is a lowered risk of problems such as seeding and false-body.

The following table gives processing temperature guidelines for some solvent systems commonly used in coatings:

  • Aliphatic hydrocarbons 35 - 75°C (95 - 167°F)
  • Aromatic hydrocarbons 30 - 50°C (86 - 122°F)
  • Aromatic hydrocarbon/ Alcohol blends 30 - 50°C (86 - 122°F)
  • Solvent free epoxy coatings 40 - 60°C (104 - 140°F)

CRAYVALLAC® MT is best incorporated during the pigment dispersion stage using a high-speed disperser operating at a temperature within the recommended guidelines.

  • In order to obtain the maximum performance from CRAYVALLAC® MT, the dispersion process should be maintained for a period of 20 – 40 minutes at the recommended temperature. The use of high-speed dispersers is ideal in that they generate both the necessary shear and temperature required for full dispersion and activation.
  • The activation process constitutes the conversion of the CRAYVALLAC® MT particles to an interacting network of fibre like particles.
  • It is this network that gives rise to the final coating’s shear thinning rheology.
  • This shear thinning characteristic provides a very high viscosity under the low shear rates associated with sedimentation, and a low viscosity at the much higher application shear rates. The net result is excellent control of sedimentation combined with ease of application.
  • Immediately following application, where low shear conditions again predominate, the coating’s viscosity undergoes a time dependent recovery as the network re- establishes itself. This time dependence is known as thixotropy and enables the final coating to attain very good levelling.
  • Activation at too low a temperature, or too high a temperature, or for too short a time, will result in the formation of an inefficient interacting network.
  • The use of too high a temperature will result in the network dissolving. Partial dissolving of CRAYVALLAC® MT during coating manufacture manifests itself on cooling in the form of seeding. This is when dissolved material crystallises out in an uncontrolled manner.
  • As with all rheology modifiers based on hydrogenated castor oil, coatings prepared using CRAYVALLAC® MT may sometimes develop an excessively high structure, or false body. This results when the hot coating is allowed to cool in the absence of stirring.
  • This effect is minimised by cooling the coating with stirring to less than 40°C (104°F) prior to discharge.
  • Fortunately, this false-body phenomenon is a temporary effect and can be removed by the application of shear.
  • Due to the potential for false-body to occur, care must be taken to ensure that process and quality control tests are not carried out on affected samples.
  • This is best achieved by pre-conditioning all samples by mechanical stirring for several minutes prior to testing. In addition to solvent-based coatings applications, CRAYVALLAC® MT has been used successfully in a multitude of other applications such as inks, adhesives, mastics, caulks, sealants, fillers, greases and lubricants.
  • Due to the multitude of formulations, processing methods and application conditions used in the field, we strongly recommend that all products containing CRAYVALLAC® MT be tested thoroughly to ensure their suitability for their intended end use.
  • In particular, application in poorly ventilated areas, or on hot substrates, or by hot spray, may require additional attention.
Performance Benefits
  • 100% Active
  • Imparts shear thinning rheology with thixotropic viscosity
  • Recovery
  • Very good sag resistance
  • Very good anti-settle properties
  • Suitable for solvent-free coatings
  • Very good recoatability

Applications & Uses

Properties

Regulatory & Compliance

Certifications & Compliance
Contains any chemicals listed on Prop 65 (including impurities, residues, catalysts, monomers, and by-products and excluding heavy metals)?

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000003
Principal

Storage & Handling

Storage Conditions
  • Use corrosion- resistant storage tanks and piping.
  • Air-operated diaphragm pumps are preferred.
  • Avoid temperature extremes.
  • Do not freeze; store between 5°- 30°C.
  • Under these conditions, the product may be stored for up to 4 years from production date.

Other

Appearance
Off white powder
Color (SDS)
Cream
Insoluble in (SDS)
Water
Item Number
Odor (SDS)
Odorless
Other Hazards
Irritation: Possible irritation of the respiratory tract (from inhalation of dust). Skin contact: Slightly irritating to skin.Eye contact: Risk of eye irritation. (mechanical effect of dust), Potentially bioaccumulative, The dust may form an explosive mixture with air. At elevated temperature: Thermal decomposition into toxic products. Decomposition products: See chapter 10
USA/DOT UN Number
Not Applicable
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life4.0 yryr
Physical Properties
ValueUnitsTest Method / Conditions
Bulk Density0.4-0.6 g/cm³g/cm³
Density1.02 g/cm³g/cm³CR 006
Particle Size4.0 µmµmInternal Method
Particle Size4.0-20.0 µmµmMalvern Mastersizer S 20 μm
Storage Temperature41.0-86.0 °F°F
Application Information
ValueUnitsTest Method / Conditions
Dosage (Use Level)0.2-1.5 %%anti-settle and sag resistance
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Autoignition Temperature (SDS)380.0 °C°C
Density (SDS)1.02 g/cm³g/cm³at 20°C
Melting Point (SDS)130.0-140.0 °C°C
Partition coefficient n-octanol/water (SDS)min. 5.86-OECD 117 n-Octanol/Water
Solid Content (SDS)100.0 %%in Solution