Enhanced TDS
Identification & Functionality
- CASE Ingredients Functions
- Chemical Family
- Chemical Name
- Country of Origin
- Function
- Rheology Modifier
- Product Code
- MITM01575
- Technologies
- Product Families
Features & Benefits
- CASE Ingredients Features
- Product Benefits
- CRAYVALLAC® MT is a micronised amide modified hydrogenated castor oil rheology modifier for solvent-based and solvent-free coatings.
- CRAYVALLAC® MT is suited to coating systems based on aliphatic hydrocarbons, aromatic hydrocarbons and aromatic hydrocarbon/alcohol blends.
- Compared to the most basic hydrogenated castor oil based rheology modifiers, CRAYVALLAC® MT is more tolerant to stronger solvents.
- The result of this is a lowered risk of problems such as seeding and false-body.
The following table gives processing temperature guidelines for some solvent systems commonly used in coatings:
- Aliphatic hydrocarbons 35 - 75°C (95 - 167°F)
- Aromatic hydrocarbons 30 - 50°C (86 - 122°F)
- Aromatic hydrocarbon/ Alcohol blends 30 - 50°C (86 - 122°F)
- Solvent free epoxy coatings 40 - 60°C (104 - 140°F)
CRAYVALLAC® MT is best incorporated during the pigment dispersion stage using a high-speed disperser operating at a temperature within the recommended guidelines.
- In order to obtain the maximum performance from CRAYVALLAC® MT, the dispersion process should be maintained for a period of 20 – 40 minutes at the recommended temperature. The use of high-speed dispersers is ideal in that they generate both the necessary shear and temperature required for full dispersion and activation.
- The activation process constitutes the conversion of the CRAYVALLAC® MT particles to an interacting network of fibre like particles.
- It is this network that gives rise to the final coating’s shear thinning rheology.
- This shear thinning characteristic provides a very high viscosity under the low shear rates associated with sedimentation, and a low viscosity at the much higher application shear rates. The net result is excellent control of sedimentation combined with ease of application.
- Immediately following application, where low shear conditions again predominate, the coating’s viscosity undergoes a time dependent recovery as the network re- establishes itself. This time dependence is known as thixotropy and enables the final coating to attain very good levelling.
- Activation at too low a temperature, or too high a temperature, or for too short a time, will result in the formation of an inefficient interacting network.
- The use of too high a temperature will result in the network dissolving. Partial dissolving of CRAYVALLAC® MT during coating manufacture manifests itself on cooling in the form of seeding. This is when dissolved material crystallises out in an uncontrolled manner.
- As with all rheology modifiers based on hydrogenated castor oil, coatings prepared using CRAYVALLAC® MT may sometimes develop an excessively high structure, or false body. This results when the hot coating is allowed to cool in the absence of stirring.
- This effect is minimised by cooling the coating with stirring to less than 40°C (104°F) prior to discharge.
- Fortunately, this false-body phenomenon is a temporary effect and can be removed by the application of shear.
- Due to the potential for false-body to occur, care must be taken to ensure that process and quality control tests are not carried out on affected samples.
- This is best achieved by pre-conditioning all samples by mechanical stirring for several minutes prior to testing. In addition to solvent-based coatings applications, CRAYVALLAC® MT has been used successfully in a multitude of other applications such as inks, adhesives, mastics, caulks, sealants, fillers, greases and lubricants.
- Due to the multitude of formulations, processing methods and application conditions used in the field, we strongly recommend that all products containing CRAYVALLAC® MT be tested thoroughly to ensure their suitability for their intended end use.
- In particular, application in poorly ventilated areas, or on hot substrates, or by hot spray, may require additional attention.
- Performance Benefits
- 100% Active
- Imparts shear thinning rheology with thixotropic viscosity
- Recovery
- Very good sag resistance
- Very good anti-settle properties
- Suitable for solvent-free coatings
- Very good recoatability
Applications & Uses
- Coating End Applications
- Markets
- Applications
Properties
- Physical Form
- Soluble In
Regulatory & Compliance
- Certifications & Compliance
- Contains any chemicals listed on Prop 65 (including impurities, residues, catalysts, monomers, and by-products and excluding heavy metals)?
Packaging & Availability
- Packaging Type
Principal Information
- Group Principal Number
- S000003
- Principal
Storage & Handling
- Storage Conditions
- Use corrosion- resistant storage tanks and piping.
- Air-operated diaphragm pumps are preferred.
- Avoid temperature extremes.
- Do not freeze; store between 5°- 30°C.
- Under these conditions, the product may be stored for up to 4 years from production date.
Other
- Appearance
- Off white powder
- Color (SDS)
- Cream
- Insoluble in (SDS)
- Water
- Item Number
- Odor (SDS)
- Odorless
- Other Hazards
- Irritation: Possible irritation of the respiratory tract (from inhalation of dust). Skin contact: Slightly irritating to skin.Eye contact: Risk of eye irritation. (mechanical effect of dust), Potentially bioaccumulative, The dust may form an explosive mixture with air. At elevated temperature: Thermal decomposition into toxic products. Decomposition products: See chapter 10
- USA/DOT UN Number
- Not Applicable
- Shelf Life & Stability
Value Units Test Method / Conditions Shelf Life 4.0 yr yr - Physical Properties
Value Units Test Method / Conditions Bulk Density 0.4-0.6 g/cm³ g/cm³ Density 1.02 g/cm³ g/cm³ CR 006 Particle Size 4.0 µm µm Internal Method Particle Size 4.0-20.0 µm µm Malvern Mastersizer S 20 μm Storage Temperature 41.0-86.0 °F °F - Application Information
Value Units Test Method / Conditions Dosage (Use Level) 0.2-1.5 % % anti-settle and sag resistance - SDS Physical and Chemical Properties
Value Units Test Method / Conditions Autoignition Temperature (SDS) 380.0 °C °C Density (SDS) 1.02 g/cm³ g/cm³ at 20°C Melting Point (SDS) 130.0-140.0 °C °C Partition coefficient n-octanol/water (SDS) min. 5.86 - OECD 117 n-Octanol/Water Solid Content (SDS) 100.0 % % in Solution