3M™ Glass Bubbles S22

3M™ Glass Bubbles S22 is specially formulated for a high strength-to-weight ratio. This allows greater survivability under many demanding processing conditions, such as injection molding. They also produce stable voids, which results in low thermal conductivity and a low dielectric constant. 3M glass bubbles are available in a variety of sizes and grades to help you meet your product and processing requirements.

Principal: 3M Advanced Materials

Functions: Filler

Chemical Family: Borosilicates

Processing Methods: Casting, Injection Molding, Molding, Spraying

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Identification & Functionality

Blend
No
Chemical Family
Chemical Name
Country of Origin
Function
Filler
Plastics & Elastomers Functions
Product Code
MITM00077
Single Ingredient
Yes
Synonyms
Glass, oxide, chemicals, Oxide glass chemicals, Glass Fiber
Technologies
Product Families

Features & Benefits

Applications & Uses

Properties

Physical Form
Typical Properties

Chemical Resistance: 

  • In general, the chemical properties of 3M™ Glass Bubbles S22 resemble those of a soda-lime-borosilicate glass.
  • Conductivity increases with temperature and product density.
  • The thermal conductivity of a composite will depend on the matrix material and volume loading of 3M™ Glass Bubbles S22.

Thermal Stability: 

  • Appreciable changes in bubble properties may occur above 1112°F (600°C) depending on temperature and duration of exposure.

Hard Particles:

  • No hard particles (e.g. glass slag, flow agent, etc.) greater than U.S. number 40 (420 microns) standard sieve will exist.
  • Using a 10 gram sample on a U.S. number 200 standard sieve (74 microns), a maximum of five (5) percent by weight glass bubbles will be retained on the sieve.

Flow:

  • 3M™ Glass Bubbles S22 remain free flowing for at least one year from the date of shipment if stored in the original, unopened container in the minimum storage conditions of an unheated warehouse.

Regulatory & Compliance

Safety & Health

Safety Information

Dusting problems that may occur while handling and processing can be minimized by the following procedures:

  1.  For eye protection wear chemical safety goggles. For respiratory system protection wear an appropriate NIOSH/ MSHA approved respirator. 
  2. Use appropriate ventilation in the work area.
  3. Pneumatic conveyor systems have been used successfully to transport 3M glass bubbles without dusting from shipping containers to batch mixing equipment.
  • Static eliminators should be used to help prevent static charges.
  • Diaphragm pumps have been used to successfully convey 3M glass bubbles.
  • Vendors should be consulted for specific recommendations.
  • 3M glass bubble breakage may occur if the product is improperly processed.
  • To minimize breakage, avoid high shear processes such as high speed Cowles Dissolvers, point contact shear such as gear pumps or 3-roll mills, and processing pressures above the strength test pressure for each product.

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S002409
Principal

Storage & Handling

Storage Conditions
  • To help ensure ease of storage and handling while maintaining free flowing properties, 3M™ Glass Bubbles S22 have been made from a chemically stable glass and are packaged in a heavy-duty polyethylene bag within a cardboard container.
  • Minimum storage conditions should be unopened cartons in an unheated warehouse.
  • Under high humidity conditions with an ambient temperature cycling over a wide range, moisture can be drawn into the bag as the temperature drops and the air contracts.
  • The result may be moisture condensation within the bag.
  • Extended exposure to these conditions may result in “caking” of the 3M glass bubbles to various degrees.

To minimize the potential for “caking” and prolong the storage life, the following suggestions are made:

  1. Carefully re-tie open bags after use.
  2. If the polyethylene bag is punctured during shipping or handling, use this bag as soon as possible, patch the hole, or insert the contents into an undamaged bag.
  3. During humid summer months, store in the driest, coolest space available.
  4. If good storage conditions are unavailable, carry a minimum inventory, and process on a first in/first out basis.

Other

Appearance
White to the unaided eye
Color (SDS)
White
Item Number
Odor (SDS)
Odorless
USA/DOT UN Number
Not Applicable
Thermal Properties
ValueUnitsTest Method / Conditions
Thermal Conductivity0.076 W/m·KW/m·Kat 21°C
Thermal Stability1112.0 °F°F
Chemical Properties
ValueUnitsTest Method / Conditions
Alkalinitymax. 0.5 meq/gmeq/g
pH9.1-9.9-
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life730.0 dd
Electrical Properties
ValueUnitsTest Method / Conditions
Dielectric Constant1.2-2.0-at 100 MHz
Mechanical Properties
ValueUnitsTest Method / Conditions
Isostatic Crush Strength400.0 psipsiIsostatic Crush Strength, 80% Minimum Fractional Survival, 90% Target Fractional Survival
Physical Properties
ValueUnitsTest Method / Conditions
Density0.19-0.25 g/cm³g/cm³
Flotationmin. 90.0 %(V/V)%(V/V)bulk volume
Oil Absorption0.2-0.6 g/cm³g/cm³
Sieve Fractionation (Retained)5.0 %(W/W)%(W/W)Tyler Standard Screen using a 10g sample, retained on the sieve
Material Composition
ValueUnitsTest Method / Conditions
Volatile Contentmax. 0.5 %(W/W)%(W/W)
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Density (SDS)0.1-0.6 g/cm³g/cm³
Softening Point (SDS)min. 600.0 °C°C
Specific Gravity (SDS)0.1-0.6-
Volatile Content (SDS)max. 0.5 %(W/W)%(W/W)