3M™ Glass Bubbles HGS4K28

3M™ Glass Bubbles HGS4K28, when drilling and cementing across highly depleted zones and weaker formations, low-density systems are required to prevent/minimize problems associated with excessive overbalance conditions including fluid loss/lost circulation, differential sticking, minimal penetration rates, formation damage, and reduced well productivity.

Principal: 3M Advanced Materials

Functions: Filler, Filler

Chemical Family: Borosilicates

End Uses: Aerospace Syntactic Foam, Cement Slurry, Hydrospace Syntactic Foam, Oil & Gas Applications, Printed Wire Boards, Radomes

Applicable Processes: Downhole Drilling, Drilling Applications, Oil Well Cementing

Processing Methods: Casting, Injection Molding, Molding, Spraying

Features: Broad Effective Density, Cost Effective, High Filler Loading, High Strength, High Strength To Weight Ratio, Impact Resistance, Improved Flow, Improved Well Integrity, Improves Consistency, Improves Penetration, Increased Well Productivity, Lightness, Long Shelf Life, Low Alkalinity, Low Density, Low Thermal Conductivity, Low Viscosity, Low Warpage, Minimize Shrinkage, Reduced Fluid Loss, Reduces Differential Sticking, Shear Resisitance, Viscosity Stability, Water Resistance

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Enhanced TDS

Identification & Functionality

Blend
No
Chemical Family
Chemical Name
Country of Origin
Industrial Additives Functions
Plastics & Elastomers Functions
Product Code
MITM16032
Single Ingredient
Yes
Synonyms
Glass, oxide, chemicals, Oxide glass chemicals, Glass Fiber
Technologies
Product Families

Features & Benefits

Applications & Uses

Applicable Processes
Industrial Additives End Use
Plastics & Elastomers End Uses
Plastics & Elastomers Processing Methods
Markets
Applications
Processing Information

3M™ Glass Bubbles HGS4K28 breakage may occur if the product is improperly processed. To minimize breakage, avoid high shear processes, point contact shear such as gear pumps or 3-roll mills, and processing pressures above the strength test pressure for each product.

Properties

Physical Form
Stability Data

Appreciable changes in 3M™ Glass Bubbles HGS4K28 properties may occur above 1112°F (600°C) depending on temperature and duration of exposure.

Regulatory & Compliance

Technical Details & Test Data

Technical Data

3M™ Glass Bubbles HGS4K28 in drilling, completion and work-over fluids

  • Eliminate the need for specialized equipment used in foamed cement
  • Compatible with both water and oil based systems
  • More economical and allow a greater density reduction window than synthetic oils
  • Helps achieve and maintain the target density throughout the drilling operation:
  1. Light - when synthetic oils are used as base fluid, densities as low as 5.5 lb/gal (0.66 kg/l) can be achieved.
  2. Tiny - 3M™ Glass Bubbles HGS8000X and 3M™ Glass Bubbles HGS4K28 remain in the fluid when circulating through solids control equipment, including shale shakers, hydrocyclones and centrifuges.
  3. Tough - resistant to shear and impact forces when circulating through bit nozzles and impacting formation walls.
  • Offer the potential for higher performance through increased rate of penetration (ROP).
  • Reduce your cost through reconditioning and reuse of the lightweight fluid.

3M™ Glass Bubbles HGS4K28 in cementing:

  • Consistency batch-to-batch, location-to-location
  • Broad effective density at any pressure
  • Improved density reduction capacity – cement slurry density values below 9.0 lb/gal (1.1 kg/l) have been achieved.
  • Low-density, high-strength 3M Glass Bubbles HGS Series are lighter and stronger and help achieve higher strength-to-weight cement designs.
  • Light weight cement slurries made with 3M Glass Bubbles HGS series help prevent problems associated with fluid loss/lost circulation such as reduced top of cement (TOC) and thus the need for remedial squeeze. Additional benefits include the potential for:
  1. Reduced Wait-On-Cement (WOC)
  2. Reduced need for multi-staging
Density vs Pressure Graph

3M™ Glass Bubbles K15 effective densities at pressure

 

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Safety & Health

Safety Precautions

For worker protection, please follow your company’s procedures for safety and proper PPE, and consider the following:

  • Select and use eye/face protection to prevent contact based on the results of an exposure assessment. Safety Glasses with side shields are recommended.
  • Wear respiratory protection if ventilation is inadequate to prevent overexposure. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for particulates. (For additional information about personal protective equipment, refer to the product Safety Data Sheet.)
  • Provide local exhaust ventilation at transfer points. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/ or control dust. If ventilation is not adequate, use respiratory protection equipment.

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S002409
Principal

Storage & Handling

Storage Conditions

Storage: Ideal storage conditions include unopened cartons in a dry and temperature-controlled warehouse.

Extended exposure of 3M™ Glass Bubbles HGS4K28 boxes to high humidity and/or conditions susceptible to condensation may result in some amount of “caking” of the 3M™ Glass Bubbles HGS4K28. To minimize the potential for caking and thereby maximize storage life, the following suggestions are offered:

  • Carefully re-tie opened bags immediately after use. 
  • If the polyethylene bag is punctured during shipping or handling, seal the hole as soon as possible or insert the contents into an undamaged bag.
  • During hot and/or humid months, store boxes in the driest, coolest space available.

If controlled storage conditions are unavailable, carry a minimum inventory and process on a first in/ first out basis.
Handling: Due to the low weight and small particle size of 3M™ Glass Bubbles HGS4K28, dusting may occur while handling and processing. To minimize the dusting potential during handling,
consider the following: 

  • Do not open 3M™ Glass Bubbles HGS4K28 packages until ready to use.
  • Upon opening, have an air siphon near the opening to pull away airborne particles. (Dust collection equipment may be required – check local OSHA and other applicable regulations.)
  • Remove 3M™ Glass Bubbles HGS4K28 with a suction “wand” (with slight positive pressure aeration) and transfer to a closed mixing tank inside fully contained piping. If a closed mixing tank is not available, use dust collection equipment as close as practical to the point of entry. Pneumatic conveyor systems have been used successfully to transport 3M™ Glass Bubbles HGS4K28 without dusting from shipping containers to batch mixing equipment. Equipment vendors should be consulted for recommendations.
  • Static eliminators should be used to prevent static buildup.

Other

Appearance
White to the unaided eye
Color (SDS)
White
Item Number
Odor (SDS)
Odorless
USA/DOT UN Number
Not Applicable
Chemical Properties
ValueUnitsTest Method / Conditions
Alkalinitymax. 0.5 meq/gmeq/g
pH9.2-9.5-
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life2.0 yryr
Mechanical Properties
ValueUnitsTest Method / Conditions
Isostatic Crush Strength4000.0 psipsiNitrogen Isostatic Crush Strength, 80% Minimum Fractional Survival, 90% Target Fractional Survival, in glycerol
Physical Properties
ValueUnitsTest Method / Conditions
Density0.25-0.31 g/cm³g/cm³
Density0.28 g/cm³g/cm³Nominal
Particle Size30.0 µmµmD50
Particle Size45.0 µmµmInternal Method 90% vol.
Particle Size20.0 µmµmInternal Method by volume, 10% distribution
Particle Size30.0 µmµmInternal Method D50, by volume
Solubility in Mud Acid0.9995 %(W/W)%(W/W)
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Density (SDS)0.25-0.63 g/cm³g/cm³
Softening Point (SDS)min. 600.0 °C°C
Specific Gravity (SDS)0.25-0.63-
Volatile Content (SDS)max. 0.5 %(W/W)%(W/W)