3M™ Glass Bubbles S35

3M™ Glass Bubbles S35 are engineered hollow glass microspheres that are alternatives to conventional fillers and additives such as silicas, calcium carbonate, talc, clay, etc., for many demanding applications. These low-density particles are used in a wide range of industries to reduce part weight, lower costs and enhance product properties. The unique spherical shape of 3M glass bubbles offers a number of important benefits, including: higher filler loading, lower viscosity/improved flow and reduced shrinkage and warpage. It also helps the 3M™ Glass Bubbles S35 blend readily into compounds and makes them adaptable to a variety of production processes including spraying, casting and molding.

Principal: 3M Advanced Materials

Functions: Filler

Chemical Family: Borosilicates

End Uses: Golf Balls, PVC-based Sealants, Syntactic Foams

Processing Methods: Casting, Extrusion, Injection Molding, Molding, Pultrusion, Resin Transfer Molding, Spraying

Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Chemical Name
Country of Origin
Function
Filler
Plastics & Elastomers Functions
Product Code
MITM00079
Single Ingredient
Yes
Synonyms
Glass, oxide, chemicals, Oxide glass chemicals, Glass Fiber
Technologies
Product Families

Features & Benefits

Applications & Uses

Adhesive & Sealant End Applications
Industrial Additives End Use
Plastics & Elastomers End Uses
Plastics & Elastomers Processing Methods
Markets
Applications

Properties

Physical Form
Typical Properties

Typical Properties

Chemical Resistance:

  • In general, the chemical properties of 3M™ Glass Bubbles S38 resemble those of a soda-lime-borosilicate glass.
  • Conductivity increases with temperature and product density.
  • The thermal conductivity of a composite will depend on the matrix material and volume loading of 3M™ Glass Bubbles S38.

Thermal Stability:

  • Appreciable changes in bubble properties may occur above 1112°F (600°C) depending on temperature and duration of exposure.

pH:

  • Because 3M glass bubbles are a dry powder, pH is not defined.
  • The pH effect will be determined by the alkalinity as indicated above.
  • When 3M glass bubbles are mixed with deionized water at 5% volume loading, the resulting pH of the slurry is typically 9.1 to 9.9, as measured by a pH meter.

Hard Particles:

  • No hard particles (e.g. glass slag, flow agent, etc.) greater thanU.S. number 40 (420 microns) standard sieve will exist.

Oversize Particles:

  • Using a 10 gram sample on a U.S. number 140 standard sieve (105 microns), a maximum of three (3) percent by weight glass bubbles will be retained on the sieve.

Flow:

  • 3M™ Glass Bubbles S38 remain free flowing for at least one year from the date of shipment if stored in the original, unopened container in the minimum storage conditions of an unheated warehouse.
pH Information

Because 3M™ Glass Bubbles K15 are a dry powder, pH is not defined. The pH effect will be determined by the alkalinity as indicated above. When 3M glass bubbles are mixed with deionized water at 5% volume loading, the resulting pH of the slurry is typically 9.1 to 9.9, as measured by a pH meter.

Regulatory & Compliance

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S002409
Principal

Storage & Handling

Storage Conditions

To help ensure ease of storage and handling while maintaining free flowing properties, 3M™ Glass Bubbles K15 have been made from a chemically stable glass and are packaged in a heavy-duty polyethylene bag within a cardboard container.

Minimum storage conditions should be unopened cartons in an unheated warehouse.

Under high humidity conditions with an ambient temperature cycling over a wide range, moisture can be drawn into the bag as the temperature drops and the air contracts. The result may be moisture condensation within the bag. Extended exposure to these conditions may result in “caking” of the 3M glass bubbles to various degrees. To minimize the potential for “caking” and prolong the storage life, the following suggestions are made:

  • Carefully re-tie open bags after use.
  • If the polyethylene bag is punctured during shipping or handling, use this bag as soon as possible, patch the hole, or insert the contents into an undamaged bag.
  • During humid summer months, store in the driest, coolest space available.
  • If good storage conditions are unavailable, carry a minimum inventory, and process on a first in/first out basis.

 

Dusting problems that may occur while handling and processing can be minimized by the following procedures:

  • For eye protection wear chemical safety goggles. For respiratory system protection wear an appropriate NIOSH/ MSHA approved respirator. (For additional information about personal protective equipment, refer to Material Safety Data Sheet.)
  • Use appropriate ventilation in the work area.
  • Pneumatic conveyor systems have been used successfully to transport 3M glass bubbles without dusting from shipping containers to batch mixing equipment. Static eliminators should be used to help prevent static charges. Diaphragm pumps have been used to successfully convey 3M™ Glass Bubbles K15. Vendors should be consulted for specific recommendations. 

3M™ Glass Bubbles K15 breakage may occur if the product is improperly processed. To minimize breakage, avoid high shear processes such as high speed Cowles Dissolvers, point contact shear such as gear pumps or 3-roll mills, and processing pressures above the strength test pressure for each product.

Other

Appearance
White to the unaided eye
Color (SDS)
White
Item Number
Odor (SDS)
Odorless
Temperature Control
No
USA/DOT UN Number
Not Applicable
Chemical Properties
ValueUnitsTest Method / Conditions
Alkalinitymax. 0.5 meq/gmeq/g
pH9.1-9.9-pH Meter
Electrical Properties
ValueUnitsTest Method / Conditions
Dielectric Constant1.2-1.7-at 100 MHz
Material Composition
ValueUnitsTest Method / Conditions
Volatile Contentmax. 0.5 %(W/W)%(W/W)
Mechanical Properties
ValueUnitsTest Method / Conditions
Isostatic Crush Strength3000.0 psipsiIsostatic Crush Strength, 80% Minimum Fractional Survival, 90% Target Fractional Survival
Physical Properties
ValueUnitsTest Method / Conditions
Density0.32-0.38 g/cm³g/cm³
Oil Absorption0.2-0.6 g/100cm³g/100cm³ASTM D281
Particle Size20.0 µmµmInternal Method 10%, by volume
Particle Size40.0 µmµmInternal Method 50%, by volume
Particle Size65.0 µmµmInternal Method by volume, 90th%
Particle Size80.0 µmµmInternal Method by volume, Effective
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Density (SDS)0.1-0.6 g/cm³g/cm³
Softening Point (SDS)min. 600.0 °C°C
Specific Gravity (SDS)0.1-0.6-
Volatile Content (SDS)max. 0.5 %(W/W)%(W/W)
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life0.0 dd
Thermal Properties
ValueUnitsTest Method / Conditions
Thermal Conductivity0.117 W/m·KW/m·Kat 21°C
Thermal Stabilitymin. 600.0 °C°C