Exolit® AP 428

Exolit® AP 428 is a fine-particle ammonium polyphosphate produced by a special method. The product is largely insoluble in water and completely insoluble in organic solvents. It is colorless, non-hygroscopic and non-flammable. Exolit® AP 428 differs from most other commercial products in the following ways, greatly reduced solubility in water lower viscosity in aqueous suspensions, lower viscosity in PU polyol suspensions.

Principal: Clariant Additives

Functions: Flame Retardant, Intumescent

Chemical Family: Ammonium Salts, Polyphosphates

End Uses: DTM Coating, Epoxy Coating, Hot Melt Adhesive, Intumescent Coating, Joinery, Paper, Polyurethane Foams, Primers, Reactive Adhesive, Solventborne Adhesive, Textile Coating, Top Coat, Wood Coating, Woodwork

Labeling Claims: Halogenated Flame Retardants-free, Non-Flammable

Features: Good Film Performance, Low Volatility, Low Water Solubility

Enhanced TDS

Identification & Functionality

Features & Benefits

Applications & Uses

Product End Uses
Markets
Applications
Product Applications
  • Intumescent coatings
    • On account of its low water solubility, Exolit® AP 428 is particularly suitable as an acid donor for intumescent coatings. Other essential components of intumescent systems include a binder, a carbon donor and a blowing agent. On exposure to flame, intumescent coatings form a carbonaceous foam which effectively shields the underlying material from temperature increases. Steel structures coated with intumescent paints can meet the requirements of fire resistance classes specified in EN, BS, ASTM, UL, Chinese Standards and others. The application of Exolit® AP 428 based intumescent coatings on wood or plastics enables these materials to qualify for Building Material Class B (EN 13501-1). Exolit® AP 428 imparts a good flame-retardant effect to adhesives and sealants when it is incorporated into the base formulation at the rate of 10 - 20%.
  • Polyurethane foams
    • Exolit® AP 428 is a suitable non-halogenated flame retardant for polyurethane foams. If handling of Exolit AP 428 as a solid is not possible we recommend the dosage of the flame retardant by preparing an Exolit® AP 428/polyol-suspension. Because of the low acid number of Exolit AP 428, it is also possible to incorporate this flame retardant in an Exolit® AP 428/isocyanate suspension. To prevent the solids from settling, the Exolit AP 428 suspensions should be stirred or circulated by pump. The stirrers commonly found in service tanks are adequate for this purpose.
  • Other applications
    • Exolit® AP 428 has an excellent flame-retardant effect in cellulose-containing materials such as paper and wood products. With chipboard products, A B-classification according to EN 13501-1 can be achieved by adding 15 - 20% Exolit® AP 428. Because of its high heat stability, Exolit® AP 428 is an essential component in intumescent formulations for thermoplastics, particularly polypropylene, for which the classification UL 94 V-0 is specified for applications in the electrical sector. Casting resins based on epoxy resins or unsaturated polyester resins achieve the classification UL 94 V-0 with Exolit® AP 428.

Properties

Physical Form
Soluble In

Regulatory & Compliance

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000004
Principal

Storage & Handling

Storage and Shelf Life Conditions
  • Minimum shelf life is 12 months from the date of shipping when stored according to the said conditions.

Other

Appearance (SDS)
Powder
Color (SDS)
White
Explosive Nature (SDS)
Not explosive
Flammable Nature (SDS)
Not classified as a flammability hazard
Item Number
Material Compatibility
Other Hazards
Dust can form an explosive mixture in air
Oxidizing Properties (SDS)
Not oxidizing
Protect from Freezing
No
Temperature Control
No
USA/DOT UN Number
Not Applicable
Chemical Properties
ValueUnitsTest Method / Conditions
Acid Numbermax. 1.5mg KOH/g
Nitrogen Content14.0-15.0%(W/W)Elemental Analysis
pH6.0-8.0-
Material Composition
ValueUnitsTest Method / Conditions
Phosphorus Content31.0-32.0%(W/W)Photometer after oxidizing dissolution
Physical Properties
ValueUnitsTest Method / Conditions
Moisture Contentmax. 0.25%(W/W)Thermo-Gravimetric Analysis at 130°C
Particle Size20.0µmD50
Viscositymax. 100.0mPa.sat 25°C, 10% aqueous solution
Weight Loss5.0%(W/W)Laser Diffraction at 350°C
Weight Loss10.0%(W/W)Laser Diffraction at 450°C
Weight Loss20.0%(W/W)Laser Diffraction at 550°C
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Burning Number (SDS)1.0-Does not catch fire
Density (SDS)1.9g/cm³at 25°C
Melting Point (SDS)min. 275.0°C
Self Ignition Temperature (SDS)min. 400.0°CVDI 2263 mixed 1:1 with diatomaceous earth
Self-Accelerating Decomposition Temperature (SADT) (SDS)min. 75.0°C
pH (SDS)5.0-8.0-
pH (SDS)5.0-8.0-at concentration: 10%
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life12.0mo
Thermal Properties
ValueUnitsTest Method / Conditions
Decomposition Temperaturemin. 275.0°C