Exolit® RP 607

Exolit® RP 607 is a flame retardant based on red phosphorus. Due to a unique stabilization it is noted for its high oxidation and thermal stability. Exolit RP 607 is a fine brownish- red powder, insoluble in water and organic solvents. Due to the combination of stabilization and microencapsulation, the material is mostly inert against atmospheric influences.

Principal: Clariant Additives

Chemical Family: Phosphorous-based Compounds

Functions: Flame Retardant

Compatible Polymers & Resins: Polyamides, Polyesters, Polyolefins, Polystyrenes (PS), Polyurethanes (PU)

End Uses: Foams

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Enhanced TDS

Identification & Functionality

Chemical Family
Function
Flame Retardant
Plastics & Elastomers Functions
Product Code
MITM02904
Technologies
Product Families

Features & Benefits

Labeling Claims
Materials Features
Product Benefits
  • Mostly inert against atmospheric influences due to the combination of stabilization and microencapsulation. High oxidation and thermal stability because of a unique stabilization
  • Can be used in a large number of plastics alone or in combination with nitrogen- or halogen-containing flame-retardants
  • Insoluble in water and organic solvents
  • Particularly effective when used with condensation polymers such as polyamides, polyesters, polyurethanes, polyisocyanurates and epoxy resins
  • For polyolefins and polystyrene we recommend the combination with synergists
  • Can be used for solid plastics, closed cell foams, polymer adhesives at processing temperatures up to 300°C
  • Non-halogenated flame retardant with favorable environmental and health profile

Applications & Uses

Compatible Polymers & Resins
Plastics & Elastomers End Uses
Product Applications
  • Exolit RP 607 can be used alone or with nitrogen- or halogen-containing flame retardants in a wide range of plastics.
  • Particularly effective in condensation polymers such as polyamides, polyesters, polyurethanes, polyisocyanurates, and epoxy resins.
  • For polyolefins and polystyrene, synergists are recommended.
  • It is essential to conduct tests with graduated quantities to determine the optimum concentration of Exolit RP 607 for each case.
  • The best results are typically achieved with an addition of 2% to 10%, depending on the plastic type.
  • Suitable for use in solid plastics, closed-cell foams, and polymer adhesives at processing temperatures up to 300 °C.
  • The inherent red-brown color of Exolit RP 607 is transferred to any translucent and/or light-colored product it is added to.

Properties

Physical Form

Regulatory & Compliance

Certifications & Compliance
Contains any chemicals listed on Prop 65 (including impurities, residues, catalysts, monomers, and by-products and excluding heavy metals)?

Safety & Health

Safety Information
  • The product reacts explosively with oxidizing agents.
  • During decomposition or combustion, yellow phosphorus and/or phosphorus pentoxide are formed.
  • When processing is carried out, particularly at elevated temperatures, small amounts of phosphine may be formed, especially in the presence of water.
  • As phosphine is a toxic gas, an effective extraction facility must be provided.
  • Exolit RP 607 containers must be closed tightly whenever any of the content is removed.
  • All handling operations must be carried out with due care, using only tools made from soft material (plastic, wood, etc.).
  • Do not cut the metal bag closure or the bag itself.
  • If fire breaks out, the most suitable extinguishing agents are water spray, foam, wet sand, and fire blankets.
  • Fire extinguishers that operate under gas pressure are not suitable because they tend to whip up the red phosphorus powder and thus cause the fire to spread.
  • Areas where fires involving red phosphorus powder have been extinguished should be doused several times with 2% potassium permanganate or with 10% soda or copper sulfate solution to render harmless the toxic and spontaneously flammable yellow phosphorus formed during the fire.
  • Any mechanical movement of Exolit RP 607 as well as all operations in which Exolit RP 607 is exposed to intense heat, pressure, etc. should be carried out in an inert gas atmosphere (nitrogen or argon).

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000004
Principal

Storage & Handling

Storage and Shelf Life Conditions

Minimum shelf life is 12 months from the date of shipping when stored according to the said conditions.

Other

ADR/RID/ADN Hazard Identification Number
40
ADR/RID/ADN Proper Shipping Name
Phosphorus, amorphous, mixture
ADR/RID/ADN UN Number
UN 1338
Appearance
Fine brownish-red powder
Appearance (SDS)
Powder
Color (SDS)
Red brown
Dust Explosion Class (SDS)
ST3 Capable of dust explosion
Explosive Nature (SDS)
Not explosive
IATA/ICAO Hazard Identification Number
40
IATA/ICAO Proper Shipping Name
Phosphorus, amorphous, mixture
IATA/ICAO UN Number
UN 1338
IMO/IMDG EmS Fire
F-A
IMO/IMDG EmS Spill
S-G
IMO/IMDG Proper Shipping Name
Phosphorus, amorphous, mixture
IMO/IMDG UN Number
UN 1338
Insoluble in (SDS)
Water
Item Number
Odor (SDS)
Odorless
Other Hazards
Risk of dust explosion.
USA/DOT UN Number
Not Applicable
Chemical Properties
ValueUnitsTest Method / Conditions
pH7.0-potentiometric method at 10 vol% suspension in acteone and water
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life12.0mo
Physical Properties
ValueUnitsTest Method / Conditions
Bulk Density0.8-1.2g/cm³
Density2.0g/cm³
Material Composition
ValueUnitsTest Method / Conditions
Phosphorus Contentmin. 95.0%(W/W)Photometer after oxidizing dissolution
Phosphorus Contentmin. 95.0%(W/W)
Application Information
ValueUnitsTest Method / Conditions
Dosage (Use Level)2.0-10.0%
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Autoignition Temperature (SDS)min. 340.0°CVDI 2263
Bulk Density (SDS)700.0-1200.0kg/m³at 20°C
Burning Number (SDS)5.0-ESCIS Volume 1
Burning Number (SDS)5.0-VDI 2263
Burning Rate (SDS)3.3-5.6mm/sDirective 92/69/EEC, A.10
Decomposition Temperature (SDS)min. 400.0°CDifferential Thermal Analysis heating rate 1 K/min
Density (SDS)approx. 2.2g/cm³
Ignition Energy (SDS)approx. 0.1MJ
Melting Point (SDS)600.0°Cat 42.000 hPa, decomposition
Relative Density (SDS)2.2-at 20°C
Self Ignition Temperature (SDS)300.0°CVDI 2263 Grewer
Vapor Pressure (SDS)100.0hPaat 300°C
Vapor Pressure (SDS)1000.0hPaat 400°C
pH (SDS)7.0-at 20°C