CYMEL® 323

CYMEL® 323 is a crosslinking agent that offers fast cure, humidity resistance, improved film hardness, and solvent resistance in CASE ingredients.

Principal: allnex Crosslinkers

Functions: Crosslinking Agent

Chemical Family: Chemical Mixtures & Blends

Compatible Polymers & Resins: Acrylics, Alkyds, Epoxies (EP), Polyesters

Labeling Claims: Low Formaldehyde

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Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Carrier
Chemical Family
Function
Crosslinking Agent
Product Code
MITM00241
Single Ingredient
Yes
Technologies
Product Families
Chemical Structure

CYMEL® 323

Features & Benefits

Applications & Uses

Compatible Polymers & Resins
Product Applications

In solvent borne systems:

  • CYMEL® 323 Resin is a methylated melamine-formalde- hyde crosslinking agent with a medium to high degree of alkylation, a low methylol content and medium to high imino functionality.
  • CYMEL® 323 Resin is a very effective crosslinking agent for backbone polymers containing hydroxyl, amide and, to some extent, carboxyl functional groups, such as epoxy, alkyd/polyester or acrylic resins.
  • CYMEL® 323 Resin is suitable for a wide range of industrial stoving systems, providing exceptional fast cure response.
  • The baking volatiles from CYMEL® 323 Resin contain very low levels of formaldehyde even though the tendency to self condensation takes prefer- ence over the crosslinking reaction. Compared to other high imino, methylated crosslinking agents, CYMEL® 323 Resin shows improved film hardness, solvent and humid- ity resistance.

In water borne systems:

  • CYMEL® 323 Resin is soluble in water, and has an excel- lent compatibility with water soluble backbone polymers.
  • The carboxyl functionality of anionic backbone polymers is sufficiently acidic to catalyze the reaction at relatively low temperature curing schedules.
  • In all water bomne sys- tems where speed of cure is very important, CYMEL® 323 Resin is strongly recommended.

Catalysis:

  • CYMEL® 323 Resin requires weak acid catalysts for cure at normal baking schedules.
  • The acidity of the primary film former is usually sufficient to initiate the curing process.
  • The cure can be additionally catalyzed by weak organic or inorganic acids such as CYCAT 296-9 catalyst, which has proved to be a very effective catalyst for these systems.

Properties

Physical Form
Soluble In
Stability Data
  • Formulated systems containing CYMEL® 323 have to be stabilized with primary alcohols, amines or with a combination of these.
  • For water borne systems a pH value between 7.0-8.5 should be maintained to achieve stability.

Technical Details & Test Data

Viscosity vs Percentage Non Volatile Content Graph

Typical Thin-down Curve in Isobutanol/water (at 23°C):

CYMEL® 323 Resin

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions
  • Storage stability at ambient temperatures is minimum one year after delivery. Avoid direct sunshine.

Other

Appearance
Clear liquid
Appearance (SDS)
Viscous liquid isobutanol
Color (SDS)
Water
IATA/ICAO Proper Shipping Name
Resin solution
IATA/ICAO UN Number
UN1866
IMO/IMDG Proper Shipping Name
Resin solution
IMO/IMDG UN Number
UN1866
Item Number
Other Hazards
Not applicable
TDG Canada Proper Shipping Name
Resin solution
TDG Canada UN Number
UN1866
USA/DOT Proper Shipping Name
Resin solution
USA/DOT UN Number
UN1866
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 70.0 APHAAPHA
Color Scalemax. 70.0 GardnerGardnerISO 6271
Chemical Properties
ValueUnitsTest Method / Conditions
Free Formaldehyde Content0.3 %%ISO 9020
pH7.0-8.5-
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life1.0 yryr
Physical Properties
ValueUnitsTest Method / Conditions
Density1120.0 kg/m³kg/m³ISO 2811 at 23°C
Flash Point33.0 °C°CISO 3679
Viscosity2500.0-7500.0 mPa.smPa.sat 23°C
Viscosity2500.0-7500.0 mPa.smPa.s
Viscosity2500.0-7500.0 mPa.smPa.sISO 3219 at 23°C
Material Composition
ValueUnitsTest Method / Conditions
Non-Volatile Content78.0-82.0 %%at 45°C, foil, 45 min
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Boiling Point (SDS)108.0 °C°C
Density (SDS)1.134 g/cm³g/cm³
Evaporation Rate (SDS)0.62 %%Butyl acetate = 1
Flammable Limits (SDS)1.2-10.9 %(V/V)%(V/V)
Flash Point (SDS)33.0 °C°CPensky-Martens Closed Cup (PMCC)
Relative Vapor Density (SDS)2.55-Air = 1
Vapor Pressure (SDS)10.0 mm Hgmm HgAt 22°C
Volatile Content (SDS)20.0 %(W/W)%(W/W)
pH (SDS)6.0-9.0-