CYMEL® 323

CYMEL® 323 is a crosslinking agent that offers fast cure, humidity resistance, improved film hardness, and solvent resistance in CASE ingredients.

Principal: allnex Crosslinkers

Functions: Crosslinking Agent

Chemical Family: Melamine Formaldehydes (MF)

Compatible Polymers & Resins: Acrylics, Alkyds, Epoxies (EP), Polyesters

End Uses: Surface Coating

Labeling Claims: Animal Products-free, Genetically Modified Organism (GMO)-free, Low Formaldehyde

Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Carrier
Chemical Family
Country of Origin
Function
Crosslinking Agent
Product Code
MITM00241
Single Ingredient
Yes
Technologies
Product Families
Chemical Structure

CYMEL® 323

Features & Benefits

Applications & Uses

Coating End Applications
Compatible Polymers & Resins
Product Applications

In solvent borne systems:

  • CYMEL® 323 Resin is a methylated melamine-formalde- hyde crosslinking agent with a medium to high degree of alkylation, a low methylol content and medium to high imino functionality.
  • CYMEL® 323 Resin is a very effective crosslinking agent for backbone polymers containing hydroxyl, amide and, to some extent, carboxyl functional groups, such as epoxy, alkyd/polyester or acrylic resins.
  • CYMEL® 323 Resin is suitable for a wide range of industrial stoving systems, providing exceptional fast cure response.
  • The baking volatiles from CYMEL® 323 Resin contain very low levels of formaldehyde even though the tendency to self condensation takes prefer- ence over the crosslinking reaction. Compared to other high imino, methylated crosslinking agents, CYMEL® 323 Resin shows improved film hardness, solvent and humid- ity resistance.

In water borne systems:

  • CYMEL® 323 Resin is soluble in water, and has an excel- lent compatibility with water soluble backbone polymers.
  • The carboxyl functionality of anionic backbone polymers is sufficiently acidic to catalyze the reaction at relatively low temperature curing schedules.
  • In all water bomne sys- tems where speed of cure is very important, CYMEL® 323 Resin is strongly recommended.

Catalysis:

  • CYMEL® 323 Resin requires weak acid catalysts for cure at normal baking schedules.
  • The acidity of the primary film former is usually sufficient to initiate the curing process.
  • The cure can be additionally catalyzed by weak organic or inorganic acids such as CYCAT 296-9 catalyst, which has proved to be a very effective catalyst for these systems.

Properties

Physical Form
Soluble In
Stability Data
  • Formulated systems containing CYMEL® 323 have to be stabilized with primary alcohols, amines or with a combination of these.
  • For water borne systems a pH value between 7.0-8.5 should be maintained to achieve stability.

Technical Details & Test Data

Viscosity vs Percentage Non Volatile Content Graph

Typical Thin-down Curve in Isobutanol/water (at 23°C):

CYMEL® 323 Resin

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions
  • Storage stability at ambient temperatures is minimum one year after delivery. Avoid direct sunshine.

Other

Appearance
Clear liquid
Appearance (SDS)
Viscous liquid
Color (SDS)
Water
IATA/ICAO Proper Shipping Name
Resin solution
IATA/ICAO UN Number
UN1866
IMO/IMDG Proper Shipping Name
Resin solution
IMO/IMDG UN Number
UN1866
Item Number
Odor (SDS)
Isobutanol
Other Hazards
Not applicable
Protect from Freezing
No
TDG Canada Proper Shipping Name
Resin solution
TDG Canada UN Number
UN1866
Temperature Control
Yes
USA/DOT Proper Shipping Name
Resin solution
USA/DOT UN Number
UN1866
Chemical Properties
ValueUnitsTest Method / Conditions
Free Formaldehyde Content0.3%ISO 9020
pH7.0-8.5-
Material Composition
ValueUnitsTest Method / Conditions
Non-Volatile Content78.0-82.0%at 45°C, foil, 45 min
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 70.0APHA
Color Scalemax. 70.0GardnerISO 6271
Physical Properties
ValueUnitsTest Method / Conditions
Density1120.0kg/m³ISO 2811 at 23°C
Flash Point33.0°CISO 3679
Storage Temperature-4.0-86.0°F
Viscosity2500.0-7500.0mPa.sat 23°C
Viscosity2500.0-7500.0mPa.s
Viscosity2500.0-7500.0mPa.sISO 3219 at 23°C
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Boiling Point (SDS)108.0°CIsopropanol
Density (SDS)1.134g/cm³
Evaporation Rate (SDS)0.62%
Flammability Limits (SDS)1.2-10.9%(V/V)
Flash Point (SDS)33.0°CPensky-Martens Closed Cup (PMCC)
Relative Vapor Density (SDS)2.55-Air=1
Vapor Pressure (SDS)10.0mm Hgat 22°C, value for isobutanol
Volatile Content (SDS)20.0%(W/W)
pH (SDS)6.0-9.0-
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life1.0yr