CYMEL® 3745N

CYMEL® 3745N Resin is a highly methylated melamine crosslinker designed for use in both solvent-borne and waterborne industrial finishes. Its high functionality and low tendency to self-condense promotes excellent formulated stability and results in films with very good hardness development, flexibility, formability, and resistance properties making it suitable for a wide range of coating applications, like can and container coatings, foil coatings, automotive coatings and waterborne formulations.

Principal: allnex Crosslinkers

Functions: Crosslinking Agent

Chemical Family: Melamine Formaldehydes (MF)

Compatible Polymers & Resins: Acrylics, Alkyds, Epoxies (EP), Polyesters

End Uses: Can Coating, Container Coatings, Solventborne Coating, Surface Coating, Waterborne Coating

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Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Function
Crosslinking Agent
Product Code
MITM09934
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

CASE Ingredients Features
Product Benefits
  • Very high solids contents
  • Excellent deformation and film flexibility
  • Good film appearance.

Applications & Uses

Coating End Applications
Compatible Polymers & Resins
Markets
Applications
Product Applications
  • Can and container coatings
  • Foil and paper coatings
  • High solids and waterborne coatings
Formulation Information
  • The stability of formulated systems containing CYMEL® 3745N Resin can be enhanced by the addition of primary alcohols, amines or a combination of these.
  • Low molecular weight primary alcohols, such as ethanol and n-butanol, are most effective.
  • Recommended amines are DMEA or 2-AMP at a concentration of 0.5- 1.0% on total resin solids.
  • Package stability can also be enhanced by the use of a blocked acid catalyst, such as CYCAT 4045 catalyst.
  • For waterborne systems, pH should be adjusted between 7.5-8.5 to acheive optimum stability.

Properties

Physical Form
Soluble In
Catalysis Information
  • CYCAT® 3745N resin reacts according to the specific acid catalysis mechanism, consequently it will respond best to sulfonic acid catalysts, like CYCAT® 4040 or the blocked version CYCAT® 4045 catalsyt.
  • Generally 0.5 to 1.0% catalyst solution on total binder solids of the formulation is sufficient to provide good cure at baking schedules of 20 minutes at 120°C to 160°C.
  • Water-borne systems generally require temperatures of 150°C or higher to effect cure.
  • Higher concentrations of catalyst might be necessary if there are basic pigments or additives present in the formulation.
Backbone Polymer Selection
  • CYMEL® 3745N Resin contains mainly methoxymethyl functionalities making it a very effective crosslinker for backbone polymer resins containing hydroxyl, amide or carboxyl functional groups, such as those found on alkyd, polyester or acrylic resins.
  • CYMEL® 3745N Resin is very compatible with a wide range of backbone polymers and provides films with very good hardness, flexibility, formability, adhesion and resistance properties. Although the optimum level of CYMEL® 3745N Resin in a given formulation should be determined experimentally, its effective equivalent weight will be typically in the range of 130-190.

Regulatory & Compliance

Certifications & Compliance
Contains any chemicals listed on Prop 65 (including impurities, residues, catalysts, monomers, and by-products and excluding heavy metals)?

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions
  • CYMEL® 3745N Resin has a shelf life of 3 years from the date of manufacture when stored at temperatures between 5℃ and 30℃..
  • Although lower temperatures are not detrimental to stability, its viscosity will increase, possibly making the resin difficult to pump or pour.
  • The viscosity will reduce again on warming, but care should be taken to avoid excessive local heat, as this can cause an irreversible increase in viscosity.

Other

Appearance
Clear liquid
Appearance (SDS)
Liquid
Color (SDS)
Colorless
Item Number
Odor (SDS)
Formaldehyde
Other Hazards
Not applicable
USA/DOT Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S.
USA/DOT Technical name (N.O.S.)
Formaldehyde
USA/DOT UN Number
UN3082
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 70.0 APHAAPHA
Color Scalemax. 70.0 GardnerGardnerISO 6271
Chemical Properties
ValueUnitsTest Method / Conditions
Free Formaldehyde Contentmax. 0.25 %%Sulfite Method
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life3.0 yryr
Physical Properties
ValueUnitsTest Method / Conditions
Viscosity3100.0-6600.0 mPa.smPa.sCone-Plate Viscometer at 23°C
Material Composition
ValueUnitsTest Method / Conditions
Non-Volatile Contentmin. 98.0 %(W/W)%(W/W)Foil Method at 45°C, 45 min
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Density (SDS)1.2 g/cm³g/cm³
Evaporation Rate (SDS)max. 1.0 %%
Flash Point (SDS)min. 100.0 °C°C
Volatile Content (SDS)1.0 %(W/W)%(W/W)