Exolit® OP 1230

Exolit® OP 1230 is a white, fine-grained powder based on an organic phosphinate. The product is non-hygroscopic and it is insoluble in water and organic solvents. Exolit® OP flame retardants for polyamides are all based on aluminum diethyl-phosphinate (= DEPAL). The pure substance DEPAL is sold as Exolit OP 1230 and in combination with synergists as Exolit® OP 13xx types. Exolit® OP 1230 is the first non-halogenated flame retardant which can withstand the demanding requirements of this high end segment of engineering plastics.

Principal: Clariant Additives

Chemical Name: Aluminium tridiethylphosphinate

Chemical Family: Phosphinates

Functions: Flame Retardant

Compatible Polymers & Resins: Other Thermoplastics, Other Thermosets

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Enhanced TDS

Identification & Functionality

Blend
No
Chemical Family
Chemical Name
Function
Flame Retardant
Plastics & Elastomers Functions
Product Code
MITM02893
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

Labeling Claims
Materials Features
Product Benefits
  • Non-hygroscopic, insoluble in water and organic solvents
  • Good hydrolysis resistance
  • Suited as flame retardant for thermoplastics and thermosets
  • High efficiency due to its high phosphorus content
  • UL 94 V-0 rating down to 0.4 mm thickness
  • Suited for processing temperatures up to ~ 330 °C
  • Suitable for both glass fiber reinforced and unreinforced grades
  • The flame retardant polyamide compounds exhibit very good physical and excellent electrical properties
  • Suitable for lead free soldering
  • Good colorability
  • Non-halogenated flame retardant with favorable environmental and health profile

Applications & Uses

Compatible Polymers & Resins
Product Applications
  • Application:
    • Exolit® OP 1230 is suited as flame retardant for thermoplastics and thermosets. Due to its high phosphorus content the product is distinguished by a high efficiency.
    • Exolit® OP 1230 can even be applied in high temperature polyamides because of its high temperature stability. It is suitable for both glass fiber reinforced and unreinforced grades. The flame retardant polyamide compounds exhibit very good physical and electrical properties.
    • In high temperature polyamides of PA 6T/66 type, a dosage of approx. 15 % (by wt.) Exolit OP 1230 is usually sufficient to obtain the UL 94 V-0 classification for electrical compounds (at 1.6 as well as 0.8 mm thicknesses). Subject to the polymer grade, processing conditions and glass fiber reinforcement the dosage of the flame retardant may vary.
  • Processing
    • Before incorporating Exolit® OP 1230, it is important to predry the polymer as usual. If possible, the resulting moisture content should be below 0.1 % (by wt.) for high temperature polyamides, 0.05 % (by wt.) for PBT and 0.005% for PET. Predrying of Exolit® OP 1230 is not necessary. However, predrying (e. g. 4h at 120 °C) is recommended, if even very low moisture contents must be avoided.
    • Wear and corrosion protected materials are recommended for compounding and injection-molding of Exolit® OP 1230 in reinforced polyesters, high temperature polyamides, or aromatic polyamides.
    • The mixing and processing methods customary in powder processing of polymers can be used with Exolit® OP 1230.
    • The VDI Guideline 2263 “Prevention of dust fires and dust explosions” or the relevant national regulations must be observed. The optimum conditions for incorporating should be determined in each individual case. Care must be taken to ensure homogeneous dispersion of all components. The temperature of the polymer melt should not exceed 330°C.

Properties

Physical Form

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000004
Principal

Storage & Handling

Storage and Shelf Life Conditions
  • Minimum shelf life is 12 months from the date of shipping when stored according to the said conditions.

Other

Appearance (SDS)
Powder
Color (SDS)
White
Dust Explosion Class (SDS)
ST1
Item Number
Other Hazards
None known
Oxidizing Properties (SDS)
Not oxidizing
USA/DOT UN Number
Not Applicable
Thermal Properties
ValueUnitsTest Method / Conditions
Decomposition Temperaturemin. 300.0 °C°C
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life12.0 momo
Physical Properties
ValueUnitsTest Method / Conditions
Bulk Density400.0-600.0 kg/m³kg/m³
Density1.35 g/cm³g/cm³At 20°C
Moisture Contentmax. 0.2 %(W/W)%(W/W)Thermo-Gravimetric Analysis
Particle Size20.0-40.0 µmµmD50
Material Composition
ValueUnitsTest Method / Conditions
Phosphorus Content23.3-24.0 %(W/W)%(W/W)Photometer after oxidizing dissolution
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Bulk Density (SDS)400.0-600.0 kg/m³kg/m³at 20°C
Burning Number (SDS)1.0-VDI 2263-1
Decomposition Temperature (SDS)min. 572.0 °F°FDifferential Thermal Analysis
Decomposition Temperature (SDS)min. 572.0 °F°Fheating rate 5 K/min, Decomposes before melting
Density (SDS)1.35 g/cm³g/cm³Directive 92/69/EEC, A.3 at 23°C
Minimum Ignition Energy (SDS)min. 100.0 MJMJModified Hartmann tube at 20°C
Self Ignition Temperature (SDS)878.0 °F°FDIN EN 50281-2-1 Dust cloud ignition at a hot surface, Expert judgement
Self Ignition Temperature (SDS)min. 500.0 °F°FVDI 2263 Grewer
Solubility In Water (SDS)1.6 g/Lg/Lat 20°C
pH (SDS)5.0-at 20°C Concentration: 10 g/l Suspension in water