CYMEL® 325

CYMEL® 325 is a new type of highly methylated melamine-formaldehyde resin which does not require strong acid catalyst for fast cure response. CYMEL® 325 is reactive with hydroxyl amide and carboxyl group containing polymers. The weight loss of CYMEL® 325 during the baking process is significantly less than that of partially methylated melamine-formaldehyde resins. The baking volatiles from CYMEL® 325 contain very low levels of formaldehyde. The lower weight loss of CYMEL® 325 crosslinked coatings also results in less tendency to blister at higher film thickness. CYMEL® 325 requires only weak acid catalysis for cure; a low acid number in the backbone resin is suffi- cient. The cure reaction additionally can be catalyzed with weak organic acids or inorganic acids such as maleic, citric, phosphoric or alkyl phosphoric acids, low levels of p-toluene sulfonic acid or CYCAT® 14040 catalyst. CYMEL® 325 will self-condense like a partially methylated resin. Higher film hardness may, therefore, be obtained by raising the level of amino crosslinking agent. The high reaction rate of CYMEL® 325 at lower temperature reduces the chance of evaporation of low molecular weight resin components. CYMEL® 325 should, therefore, be very suitable for applications where "smoking" of the baking exhaust is a problem. Compared to partially methylated melamine-formalde- hyde resins, CYMEL® 325has shown, in some water-reducible coatings, improved humidity and salt- spray resistance. CYMEL 325 resin is FDA approved under section 121.2514 and 121.2526.

Principal: allnex Crosslinkers

Functions: Crosslinking Agent

Chemical Family: Chemical Mixtures & Blends

Compatible Polymers & Resins: Acrylics, Alkyds, Cellulose & Cellulosics, Epoxies (EP), Polyesters

End Uses: Enamel, Solventless & High Solids Coating, Surface Coating, Waterborne Coating

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Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Carrier
Chemical Family
Function
Crosslinking Agent
Product Code
MITM00242
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

CASE Ingredients Features
Product Advantages
  • Fast cure response
  • Reduced weight loss
  • Low free-formaldehyde
  • Less blistering
  • No strong acid catalyst required
  • No smoking
  • Higher resistance properties

Applications & Uses

Coating End Applications
Compatible Polymers & Resins
Markets
Applications
Dosage Information
  • CYMEL® 325 is useful in polyester and acrylic resin coil coating systems, where a minimum amount of weight loss and a high build without the danger of solvent popping during cure is desirable.
  • Since CYMEL® 325 does self-condense to some extent, some sacrifice in flexibility should be expected.
  • CYMEL® 325 is therefore recommended for prefinished metal applications where shorter dwell times or lower temperature cures are required and postforming is not of a critical nature.
  • The following formulation for a White, High Gloss, Coil Coating Enamel illustrates this application of CYMEL® 325
Product Applications
  • Automotive enamels
  • General purpose enamels
  • Coil coating
  • High solids coatings
  • Water-borne coatings

Properties

Technical Details & Test Data

Typical Film Properties

Typical film properties obtained with White Coil Coating Enamel No. 955 when applied to Alodine 1200S5 treated aluminum test panels and cured on the following schedules:

Property         Unit Test Method Condition
Oven temperature 288 260 232 260 °C - -
Dwell time 30 30 60 30 sec - -
Peak metal temperature 221 224 216 204 °C - -
Dry film thickness 0.9 1 1 1 mils - -
Color 88 89 87 87 - - Photovolt, blue filter, reflectance
Gloss 90 92 94 92 - - 60°
Gloss 73 77 75 80 - - 20°
Hardness F-H F-H F-H F-H - - Pencil
Hardness 17.1 18.6 15.2 15.2 - Knoop KHN₂₅
Impact resistance 10 10 10-20 10-20 in-lbs - Reverse
T-Bend test 10 10 10-20 10-20 - - Passes
MEK resistance 200+ 200+ 200+ 200+ - - Passes, Double rubs
Adhesion 100 100 100 100 % - Cross-hatched and taped
Peak metal temperature 249 249 249 249 °C -

Overbaked 60 seconds at 260°C

Color retention 95 95 98 98 % -

Overbaked 60 seconds at 260°C

Gloss retention, 60° 99 99 99 99 % -

Overbaked 60 seconds at 260°C

Gloss retention, 20° 96 97 100 94 % - Overbaked 60 seconds at 260°C

Safety & Health

Safety Precautions
  • Direct contact with this material can cause eye irritation and may cause skin irritation.
  • Overexposure to formalde- hyde and isobutanol vapor from this product may cause eye and respiratory tract irritation.

Packaging & Availability

Packaging Type

Other

Appearance (SDS)
Liquid
Boiling Point (SDS)
108.0 °C
Chemical Resistance (Methyl Ethyl Ketone)
min. 200.0
Color (SDS)
Clear
Color Scale
1.0 Gardner
Density
9.3 lb/gal
Density (SDS)
1.12-1.14 g/cm³
Film Thickness
0.9 Mils
Film Thickness
0.8 Mils
Flammable Limits (SDS)
1.2-10.9 %(V/V)
Flash Point (SDS)
37.0 °C
Gloss
74.0
Gloss
92.0
Gloss
68.0
Gloss
93.0
Group Principal Number
S000001
Hardness
16.9 HV
Hardness
19.6 HV
IATA/ICAO Proper Shipping Name
Resin solution
IATA/ICAO UN Number
UN1866
IMO/IMDG Proper Shipping Name
Resin solution
IMO/IMDG UN Number
UN1866
Impact Resistance
max. 10.0 in-lb
Impact Resistance
max. 10.0 in-lb
Item Number
Non-Volatile Content
78.0-82.0 %
Odor (SDS)
Formaldehyde and isobutanol
Other Hazards
Not Applicable
Principal
Relative Vapor Density (SDS)
2.55
Solid Content
70.0-74.0 %
Specific Gravity
1.24
Specific Gravity
1.12
TDG Canada Proper Shipping Name
Resin solution
TDG Canada UN Number
UN1866
USA/DOT Proper Shipping Name
Resin solution
USA/DOT UN Number
UN1866
Vapor Pressure (SDS)
10.0 mm Hg
Volatile Content (SDS)
18.0-22.0 %(W/W)
Optical Properties
ValueUnitsTest Method / Conditions
Color Scale1.0 GardnerGardnerGardner Color Scale
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Chemical Resistance (Methyl Ethyl Ketone)min. 200.0-MEK (Methyl Ethyl Ketone) Double Rub Test passes
Mechanical Properties
ValueUnitsTest Method / Conditions
Gloss74.0-at 121°C, baked 20 minutes at temperature, 20°
Gloss92.0-at 149°C, 20 mins, 60°
Gloss68.0-at 149°C, baked 20 minutes at temperature, 20°
Gloss93.0-baked 20 minutes at temperature at 121°C, 60°
Hardness16.9 HVHVat 121°C, baked 20 minutes at temperature, KHN₂₅, Knoop
Hardness19.6 HVHVat 149°C, baked 20 minutes at temperature, KHN₂₅, Knoop
Impact Resistancemax. 10.0 in-lbin-lbat 121°C, baked 20 minutes at temperature, reverse
Impact Resistancemax. 10.0 in-lbin-lbat 149°C, baked 20 minutes at temperature, Reverse
Physical Properties
ValueUnitsTest Method / Conditions
Density9.3 lb/gallb/gal
Film Thickness0.9 MilsMilsat 121°C, 20 mins
Film Thickness0.8 MilsMilsat 149°C, Baked 20 minutes at temperature
Specific Gravity1.24-resin solids
Specific Gravity1.12-solution
Material Composition
ValueUnitsTest Method / Conditions
Non-Volatile Content78.0-82.0 %%Foil Method at 45°C, 45 min
Solid Content70.0-74.0 %%
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Boiling Point (SDS)108.0 °C°C
Density (SDS)1.12-1.14 g/cm³g/cm³
Flammable Limits (SDS)1.2-10.9 %(V/V)%(V/V)
Flash Point (SDS)37.0 °C°CClosed Cup
Relative Vapor Density (SDS)2.55-Air = 1
Vapor Pressure (SDS)10.0 mm Hgmm HgAt 30°C
Volatile Content (SDS)18.0-22.0 %(W/W)%(W/W)