CYMEL® 303 LF

CYMEL® 303 LF resin is a highly methylated, monomeric melamine crosslinker supplied in liquid form at ≥ 98% solids content. Its high extent of alkylation and low tendency to self-condense make CYMEL® 303 LF resin a highly effective crosslinking agent for a broad range of applications such as can, container, automotive and general industrial coatings. While CYMEL® 303 LF resin is insoluble in water, it shows excellent compatibility with water-soluble backbone polymers and provides very good stability in amine-stabilized waterborne formulations.

Principal: allnex Crosslinkers

Functions: Crosslinking Agent

Chemical Family: Melamines

Compatible Polymers & Resins: Acrylics, Alkyds, Epoxies (EP), Polyesters

End Uses: Can Coating, Coil Coating, Container Coatings, Solventless & High Solids Coating, Surface Coating, Waterborne Coating

Labeling Claims: Solvent-free

Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Function
Crosslinking Agent
Product Code
MITM00238
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

CASE Ingredients Features
Labeling Claims
Product Benefits
  • Solvent free 
  • Excellent balance of hardness and flexibility 
  • Fast catalyzed cure response 
  • Excellent stability 
  • Low free formaldehyde

Applications & Uses

Coating End Applications
Compatible Polymers & Resins
Markets
Applications
Product Applications
  •  Coil coatings 
  • Can and container coatings 
  • Automotive finishes 
  • High solids and waterborne coatings 
  • General industrial finishes 
  • Inks

Properties

Physical Form
Soluble In
Catalysis Information
  • Because of its high extent of alkylation, CYMEL® 303 LF resin responds best to sulfonic acid catalysts, like CYCAT® 4040 catalyst or CYCAT® 600 catalyst.
  • Generally, 0.5 to 1.0% of CYCAT® 4040 catalyst on total resin solids of the formulation is sufficient to provide good cure at normal baking schedules (15 - 20 minutes at 120 - 150°C) in solvent-borne systems.
  • Water-borne systems generally require temperatures of 150°C or higher to effect cure. Higher concentrations of catalyst might be necessary if there are basic pigments or additives present in the formulation.

Technical Details & Test Data

Technical Data
  • CYMEL® 303 LF resin contains mainly methoxymethyl functional sites making it a highly effective crosslinker for backbone polymer resins containing hydroxyl, carboxyl, or amide functional groups, such as those found on alkyd, polyester, or acrylic resins.
  • Its high monomer content, and low tendency to self-condense result in films with high flexibility and formability when paired with inherently flexible polymers, such as polyester resins.
  • The effective equivalent weight of CYMEL® 303 LF is typically 130 - 190 g/eq, however, its optimum loading should be determined experimentally for each formulation with consideration of the performance properties to be optimized.

Packaging & Availability

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions
  • CYMEL® 303 LF resin has a shelf life of 1800 days from the date of manufacture when stored at temperatures below 32°C.
  • Although low temperatures are not detrimental to stability, its viscosity will increase, possibly making the resin difficult to pump or pour.
  • The viscosity will reduce again on warming, but care should be taken to avoid excessive local heat, as this can cause an irreversible increase in viscosity.
  • WARNING: CYMEL® 303 LF resin may turn hazy when cold due to crystallization of hexamethoxymethylmelamine (HMMM).
  • Warming will return the product to normal with no adverse impact on performance.

Other

Appearance (SDS)
Liquid
Color (SDS)
Colorless
Item Number
Odor (SDS)
Formaldehyde
Protect from Freezing
Yes
USA/DOT UN Number
Not Applicable
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 70.0 APHAAPHA
Color Scalemax. 1.0 GardnerGardnerDIN EN ISO 4630-1
Color Scalemax. 70.0 GardnerGardnerDIN EN ISO 6271
Color Scalemax. 1.0 GardnerGardnerGardner Color Scale
Chemical Properties
ValueUnitsTest Method / Conditions
Free Formaldehyde Contentmax. 0.1 %%Titration Method
Solvent Resistancemin. 100.0-Titration Method
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life1800.0 dd
Physical Properties
ValueUnitsTest Method / Conditions
Density9.8-10.1 lb/gallb/galASTM D1475 at 25°C
Storage Temperature41.0-86.0 °F°F
Viscosity3000.0-6000.0 mPa.smPa.sDIN EN ISO 3219 at 23°C
Viscosity2600.0-5000.0 mPa.smPa.sDIN EN ISO 3219 at 25°C
Material Composition
ValueUnitsTest Method / Conditions
Non-Volatile Contentmin. 98.0 %(W/W)%(W/W)DIN 55671 Foil, 45 mins/45°C
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Autoignition Temperature (SDS)325.0 °C°C
Density (SDS)1.1-1.3 g/cm³g/cm³
Flash Point (SDS)min. 93.0 °C°C
Vapor Pressure (SDS)18.5 mm Hgmm Hg