CYMEL® 202

CYMEL® 202 Resin is a methylated/n-butylated, high imino melamine crosslinker supplied in n-butanol. Its hydrophobic nature combined with high reactivity, high solids content, and rather low formaldehyde release during the curing process makes CYMEL® 202 Resin suitable for a wide range of medium to high solids or waterborne baking applications, like can and container coating formulations, automotive coatings, and low cure systems to improve film appearance and resistance properties. CYMEL® 202 resin has a high tendency to self-condense at rather low baking temperatures, providing films with very good hardness, gloss, chemical resistance, and outdoor durability.

Principal: allnex Crosslinkers

Functions: Crosslinking Agent

Chemical Family: Melamine Formaldehydes (MF)

Compatible Polymers & Resins: Acrylics, Alkyds, Epoxies (EP), Polyesters

End Uses: Can Coating, Container Coatings, Surface Coating

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Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Function
Crosslinking Agent
Product Code
MITM00230
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

Applications & Uses

Coating End Applications
Compatible Polymers & Resins
Markets
Applications
Formulation Stability
  • The stability of solvent-borne systems containing CYMEL® 202 Resin can be enhanced by the addition of primary alcohols, amines, or a combination of these. Low molecular weight primary alcohols such as ethanol and n-butanol are most effective.
  • Recommended amines are TEA, DMEA or 2-AMP at a concentration of 0.5-1.0% on total binder solids. For best stability in waterborne systems, a pH of 7.5-8.5 should be maintained using tertiary amines only.

Properties

Regulatory & Compliance

Certifications & Compliance
Contains any chemicals listed on Prop 65 (including impurities, residues, catalysts, monomers, and by-products and excluding heavy metals)?

Technical Details & Test Data

Catalysis Information

CYMEL® 202 Resin may not require the addition of an acid catalyst to the formulation to obtain effective cure. In many instances, the acidity of the backbone polymer in the formulation is sufficient to catalyze the reaction under normal baking conditions (15-20 minutes at 120-150°C). If catalyst addition is required, then 0.5-1.0% of CYCAT® 296-9 catalyst based on total resin solids is recommended.

Typical Thinning Curve

CYMEL® 202 Resin - Typical Thinning Curve - 1

Backbone Polymer Selection

CYMEL® 202 Resin is an effective crosslinker for backbone polymer resins containing hydroxyl, carboxyl, and amide functional groups, such as those found on alkyd, polyester or acrylic resins. Although the optimum level of CYMEL® 202 Resin should be determined experimentally, ratios of 25 to 35% based on resin solids are typically most effective.

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions
  • CYMEL® 202 Resin has a shelf life of 2 years from the date of manufacture when stored at temperatures between 5°C and 30°C. Although lower temperatures are not detrimental to stability, its viscosity will increase, possibly making the resin difficult to pump or pour.
  • The viscosity will reduce again on warming, but care should be taken to avoid excessive local heat as this can cause an irreversible increase in viscosity.

Other

Appearance
Clear liquid
Appearance (SDS)
Liquid
Color (SDS)
Clear
IATA/ICAO Proper Shipping Name
Resin solution
IATA/ICAO UN Number
UN1866
IMO/IMDG Proper Shipping Name
Resin solution
IMO/IMDG UN Number
UN1866
Item Number
Odor (SDS)
Formaldehyde and butanol
Other Hazards
Not applicable
TDG Canada Proper Shipping Name
Resin solution
TDG Canada UN Number
UN1866
USA/DOT Proper Shipping Name
Resin solution
USA/DOT UN Number
UN1866
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 70.0 APHAAPHA
Color Scalemax. 70.0 GardnerGardnerISO 6271
Chemical Properties
ValueUnitsTest Method / Conditions
Free Formaldehyde Contentmax. 0.6 %%Sulfite Method
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life2.0 yryr
Physical Properties
ValueUnitsTest Method / Conditions
Viscosity2500.0-7500.0 mPa.smPa.s
Material Composition
ValueUnitsTest Method / Conditions
Non-Volatile Content78.0-82.0 %(W/W)%(W/W)at 105°C, 3 h, Pan
Non-Volatile Content80.0-84.0 %(W/W)%(W/W)at 45°C, foil, 45 min
Application Information
ValueUnitsTest Method / Conditions
Application pH7.5-8.5-
Dosage (Use Level)0.5-1.0 %%
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Density (SDS)1.07-1.1 g/cm³g/cm³
Flash Point (SDS)47.0 °C°CSetaFlash Closed Cup
Volatile Content (SDS)16.0-22.0 %(W/W)%(W/W)