CYMEL® NF 2000A

CYMEL® NF 2000A Resin is a unique trifunctional melamine-based crosslinker containing reactive carbamate functionality supplied in n-butanol. It can be used to crosslink hydroxy- and epoxy-containing polymers to give highly durable, acid-resistant films that exhibit a favorable balance of hardness and flexibility. An important feature of CYMEL® NF 2000A Resin is that it does not contain or emit formaldehyde on cure. It can be employed as the sole crosslinker in a coating or ink formulation, or it may be used at lower levels in combination with other crosslinkers, such as amino resins or isocyanates, in order to obtain a balance of properties. CYMEL® NF 2000A Resin is recommended for high quality durable finishes such as automotive topcoats,CYMEL® NF 2000A Resin is a unique trifunctional melamine-based crosslinker containing reactive carbamate functionality supplied in n-butanol. It can be used to crosslink hydroxy- and epoxy-containing polymers to give highly durable, acid-resistant films that exhibit a favorable balance of hardness and flexibility. An important feature of CYMEL® NF 2000A Resin is that it does not contain or emit formaldehyde on cure. It can be employed as the sole crosslinker in a coating or ink formulation, or it may be used at lower levels in combination with other crosslinkers, such as amino resins or isocyanates, in order to obtain a balance of properties. CYMEL® NF 2000A Resin is recommended for high quality durable finishes such as automotive topcoats, exterior can varnishes, and coil coatings. exterior can varnishes, and coil coatings.

Principal: allnex Crosslinkers

Functions: Crosslinking Agent

Chemical Family: Triazines

Compatible Polymers & Resins: Acrylics, Alkyds, Epoxies (EP), Polyesters

End Uses: Can Coating, Coil Coating, Top Coat, Varnishes, Waterborne Coating

Labeling Claims: Formaldehyde-free, Isocyanates-free

View All Documents

Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Function
Crosslinking Agent
Product Code
MITM13488
Single Ingredient
Yes
Technologies
Product Families
Chemical Structure

CYMEL® NF 2000A Resin

Features & Benefits

CASE Ingredients Features
Labeling Claims
Product Benefits
  • Excellent environmental etch resistance
  • Excellent exterior durability
  • Non-formaldehyde chemistry
  • Non-isocyanate chemistry
  • Cure compatibility with other crosslinkers
  • Low equivalent weight / high efficiency
  • Low human toxicity

Applications & Uses

Coating End Applications
Compatible Polymers & Resins
Markets
Applications
Dosage Information
  • A significant advantage of CYMEL® NF 2000A Resin is its cure compatibility with other thermoset chemistries.
  • Since its cure response with hydroxy-functional resins is not appreciably inhibited by amines, acids, or metal catalysts, it can be used effectively as a co-crosslinking agent with other materials, such as traditional aminoplasts or isocyanates.
  • Incorporation of low levels of CYMEL® NF 2000A Resin (e.g. 1-5 wt. % on total resin solids) into a conventional polyol/aminoplast coating formulation can significantly improve the exterior durability of the cured film.
Product Applications
  • Automotive topcoats
  • Coil coatings
  • Exterior can coatings
  • Solvent-borne and waterborne coatings

Properties

Physical Form
Soluble In
Notes

¹ Product may become hazy during storage as the active ingredient is near its solubility limit in solution. The haze development has no impact on performance of the product or the clarity of resulting films.

Product Reactivity

CYMEL® NF 2000A Resin contains a combination of butyl and methyl carbamate functionality which enables it to crosslink backbone polymers containing hydroxy, epoxy and carboxy functionality.

  • Unlike conventional amino resins, CYMEL® NF 2000A Resin has very little tendency to self-react during cure, so its effective equivalent weight is in the range of 120-130.
  • In formulations where it is employed as the sole crosslinker, the level of CYMEL® NF 2000A Resin is normally adjusted to provide a ratio of 1.0 - 1.1 equivalents of carbamate functionality per equivalent of backbone polymer functionality.
  • CYMEL® NF 2000A Resin reacts with hydroxy functional backbone resins at >125°C bake schedules to form urethane linkages.
  • Cure can typically be accomplished without use of a catalyst to yield films that exhibit excellent hardness, chemical resistance, exterior durability and environmental etch resistance. Addition of low levels of acid catalyst (e.g. 0.5% dodecyl benzene sulfonic acid on binder solids) has been found to improve humidity resistance properties in some systems.
  • Both catalyzed and uncatalyzed formulations show good 1K package stability at 23°C.
  • CYMEL® NF 2000A Resin will react with carboxy functional backbone resins, but requires bake temperatures >150°C.

  • CYMEL® NF 2000A Resin reacts very efficiently with epoxy functional resins at ~125°C resulting in N-substituted carbamate and oxazolidone crosslinks.
  • Films produced through this cure mechanism often show a favorable combination of environmental etch resistance and mar resistance properties.
  • In most cases, a tertiary amine or quaternary ammonium catalyst such as 4-dimethyl- aminopyridine should be employed in the formulation.
  • However, catalyzed pot life can be limited, making it necessary to treat these as two-component systems.

 - 1

Regulatory & Compliance

Certifications & Compliance
Contains any chemicals listed on Prop 65 (including impurities, residues, catalysts, monomers, and by-products and excluding heavy metals)?

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions
  • CYMEL® NF 2000A Resin has a shelf life of 720 days from the date of manufacture when stored at temperatures below 32°C.

Other

Appearance (SDS)
Low viscosity liquid
Color (SDS)
Colorless to pale yellow
IATA/ICAO Proper Shipping Name
Flammable liquid, N.O.S.
IATA/ICAO Technical name (N.O.S.)
Butanol, tris carbamoyl triazine
IATA/ICAO UN Number
UN1993
IMO/IMDG Proper Shipping Name
Flammable liquid, N.O.S.
IMO/IMDG Technical name (N.O.S.)
Butanol, tris carbamoyl triazine
IMO/IMDG UN Number
UN1993
Insoluble in (SDS)
Water
Item Number
Odor (SDS)
Butanol
Other Hazards
Not applicable
TDG Canada Proper Shipping Name
Flammable liquid, N.O.S.
TDG Canada Technical name (N.O.S.)
Butanol, tris carbamoyl triazine
TDG Canada UN Number
UN1993
USA/DOT Proper Shipping Name
Flammable liquid, N.O.S.
USA/DOT Technical name (N.O.S.)
Butanol, tris carbamoyl triazine
USA/DOT UN Number
UN1993
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 50.0 APHAAPHA
Color Scalemax. 50.0 GardnerGardnerDIN EN ISO 6271
Turbiditymax. 2.5 NTUNTUDIN EN 27027
Chemical Properties
ValueUnitsTest Method / Conditions
pH3.0-6.0-DIN 55659-1
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life720.0 dd
Physical Properties
ValueUnitsTest Method / Conditions
Viscosity10.0-50.0 mPa.smPa.sDIN EN ISO 3219 at 23°C
Material Composition
ValueUnitsTest Method / Conditions
Non-Volatile Content48.0-52.0 %%DIN EN ISO 3251 at 105°C, 2 hrs, Pan
Sodium Contentmax. 100.0 ppmppmInductively Coupled Plasma Mass Spectrometry
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Autoignition Temperature (SDS)355.0 °C°C
Boiling Point (SDS)130.0 °C°CAt 101.3 Kpa
Density (SDS)0.99 g/cm³g/cm³
Flammable Limits (SDS)1.2-10.2 %(V/V)%(V/V)
Flash Point (SDS)42.0 °C°CDIN 53213
Vapor Pressure (SDS)4.0 mbarmbarat 20°C
Viscosity (SDS)10.0-50.0 mPa.smPa.sAt 23°C
pH (SDS)4.5-6.0-50% aqueous solution