EBECRYL® 4587

EBECRYL® 4587 is a solvent-free, water emulsifiable aliphatic urethane acrylate, for use in ultraviolet (UV) and electron beam (EB) curable coatings

Principal: allnex Radcure

Chemical Family: Polyurethanes (PU), Urethane Acrylates

End Uses: Clearcoat, Radiation Curable Coating, Solventless & High Solids Coating, Waterborne Coating

Features: Alcohol Resistance, Excellent Sandability , Excellent Scratch Resistance, Good Brilliance, High Gloss, Improved Mechanical Resistance, Solvent Resistance, Water Resistance, Yellowing Resistance

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Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Function
Binder
Product Code
MITM00326
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

CASE Ingredients Features
Labeling Claims
Performance Highlights

Ebecryl®4587 coatings are characterized by high gloss, scratch resistance, and resistance to water, alcohol, solvents, and household chemicals. Ebecryl®4587 allows formulating UV-curable waterborne coatings free of reactive thinners, solvents, and amines, as clear or pigmented systems as well as with glossy or matte finishes.

Applications & Uses

Application Method
Coating End Applications
Cure Method
Formulation Stability
  • Ebecryl®4587 can be easily emulsified in water. After the water has been flashed off, Ebecryl®4587 exhibits (with 3% photoinitiator) a UV-reactivity of approximately 7m/min. under an 80 W/cm Hg Lamp.
  • General Guidelines for Emulsifying Ebecryl®4587:

    • Take 70 parts resin and slowly stir in 30 parts tap water.

    • Emulsify in a dissolver for approximately 2 minutes at high speed (peripheral speed of the stirring disk: 20 m/s).

    • The remaining waterborne components of the formulation are added at reduced speed.

  • Storage stability must be tested prior to use as it varies in accordance with the formulation used, in particular with the addition of dispersions. Due to Ebecryl®4587 emulsions being acidic, compatibility with other components has to be checked. Experience has shown that neutralization with amine/ammonia negatively impacts storage stability.
  • If the coating can be applied immediately, the water can be added and stirred directly on site. The maximum water concentration is approximately 20%, which can be increased by the addition of 1 to 2% ethanol or acetone.
  • Non-waterborne additives must be dispersed in Ebecryl®4587 prior to emulsification. Depending on the pigment concentration, the pigmented coating should either be dispersed in pure resin or dispersed in a dissolver using a previously produced stock emulsion (approximately 75%). If dispersed in the resin, the mill base must be cooled to approximately +35°C prior to emulsification.
  • Air bubbles produced during formulation can be removed by sieving the coating, this prevents water from setting on the surface.
  • Acematt™ T5100, Acematt™ OK 412, and Deuteron™ MK have proven effective as matting agents, these should be added to the resin prior to the emulsification. Coalescing agents should not be used as they can cause cracking.
  • An Ebecryl®4587 coating can be applied in high solids formulations using conventional application methods such as spraying, rolling, and casting. The maximum coating weight should not exceed 100 g/m², otherwise, it cannot be guaranteed that the water will flash off completely before UV curing.
  • Liquid photo-initiators are required for UV curing, these are added to the resin prior to emulsification. The water must be completely flashed off prior to radiation curing.
  • Esacure™ KIP 100F was shown to be an efficient initiator for clearcoats. For pigmented coatings, we recommend trying Esacure™ KTO46. These pigmented coatings must be cured using high-pressure gallium-doped mercury vapor lamps that emit in the long wave spectrum.
  • Formulation equipment and tools can be cleaned in a 95:5 water/acetone solution.

Properties

Physical Form
Soluble In

Regulatory & Compliance

Certifications & Compliance
Contains any chemicals listed on Prop 65 (including impurities, residues, catalysts, monomers, and by-products and excluding heavy metals)?

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions
  • Storage in original sealed Allnex containers.
  • Recommended storage temperature: -10 to +35°C
  • Protect from intense radiation (light, UV), heat, and foreign material.
  • Shelf life 24 months

Other

Appearance (SDS)
Liquid
Color (SDS)
Yellowish
IATA/ICAO Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S.
IATA/ICAO Technical name (N.O.S.)
Acrylated resin
IATA/ICAO UN Number
UN3082
IMO/IMDG Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S.
IMO/IMDG Technical name (N.O.S.)
Acrylated resin
IMO/IMDG UN Number
UN3082
Immiscible In (SDS)
Water
Item Number
Odor (SDS)
Odorless
Other Hazards
Polymerization may occur from excessive heat, contamination or exposure to direct sunlight .
TDG Canada Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S.
TDG Canada Technical name (N.O.S.)
Acrylated resin
TDG Canada UN Number
UN3082
USA/DOT Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S.
USA/DOT Technical name (N.O.S.)
Acrylated resin
USA/DOT UN Number
UN3082
Optical Properties
ValueUnitsTest Method / Conditions
Iodine Color Value1.0-
Chemical Properties
ValueUnitsTest Method / Conditions
Acid Number5.0mg KOH/g
Hydroxyl Content1.0%
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life24.0mo
Physical Properties
ValueUnitsTest Method / Conditions
Density1.2g/cm³At 20°C
Flash Pointmin. 100.0°C
Viscosity1500.0mPa.sat 23°C
Material Composition
ValueUnitsTest Method / Conditions
Non-Volatile Content100.0%
Application Information
ValueUnitsTest Method / Conditions
Dosage (Use Level)1.0-2.0%ethanol or acetone
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Boiling Point (SDS)min. 165.0°CAt 1.013 Hpa
Density (SDS)1.13g/cm³at 20°C
Flash Point (SDS)156.0°CDIN EN ISO 2719 at 0.1kPa
Vapor Pressure (SDS)18.0hPaat 20°C
Viscosity (SDS)1500.0mPa.sDIN EN ISO 3219 at 23°C