RHOPLEX® CL-204

RHOPLEX® CL-104 Waterborne Acrylic Copolymer, yield clear wood coatings which shed water and coalescent rapidly, resulting in excellent early print resistance properties. However, in extreme ambient conditions (temperatures approaching 100°F (38°C) and/or very low relative humidity), some of these first generation print-resistant products can trap bubbles when spray applied, causing film haze and clarity loss. In contrast, RHOPLEX® CL-204 Acrylic Emulsion is specifically engineered to minimize this microfoam entrapment by slowing the film-set process which occurs under extreme ambient conditions, while still maintaining acceptable early print resistance properties.

Principal: Dow Coating Materials

Chemical Family: Acrylics & Acrylates

End Uses: Lacquers, Paper Coating, Top Coat, Waterborne Coating, Wood Coating

Compatible Substrates & Surfaces: Paper, Wood

Features: Chemical Resistance, Excellent Block Resistance, Excellent Print Resistance, Good Toughness, High Clarity, Mar Resistance, Prevents Microfoam Formation

Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Function
Binder
Product Code
MITM11374
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

CASE Ingredients Features
Labeling Claims
Product Features

Properties of Low Microfoam Emulsions (Coatings Applied at 100°F (38°C) and 25 Relative Humidity)

Emulsion RHOPLEX® CL-204 Acrylic Emulsion Condition
Microfoam 13 24 hr dry, (counted under microscope) Bubbles/mm²
Print Resistance³ 10 4 hr dry, 1 hour print, 2 psi / 5psi
Print Resistance³ 10 4 hr dry, 16 hours print, 2 psi / 5psi
Cold Check Resistance Pass 20 Cycles 1 cycle = 1 hour at 6°F
1 hour at 120°F
0.5 hour at RT
Stain Resistance, 24hr recovery 10 Water (6 and 24 hour spot test)
Stain Resistance, 24hr recovery 8 Ethanol (1 and 6 hour spot test)
Stain Resistance, 24hr recovery 7 Formula 409 cleaner
(1 and 6 hour spot test)
Appearance Good Clarity
Appearance Good Grain Definition
Coalescents 0.266 pounds on polymer pounds
Butyl CELLOSOLVEᵀᴹ
Coalescent
Coalescents 0.085 Butyl CARBITOLᵀᴹ Solvent

2. Measured at 70x magnification where bubbles are clearly visible.
3. Visual scale; 10 = best
Substrates: Stained cherry; unstained maple for cold check only
Sample preparation: conventional spray; 3 coats self-sealed; each coat 1 mil air dry; 30 minute air dry between coats.

Product Benefits
  • RHOPLEX® CL-204 Acrylic Emulsion is specifically engineered to minimize this microfoam entrapment by slowing the film-set process which occurs under extreme ambient conditions, while still maintaining acceptable early print resistance properties.
  • RHOPLEX® CL-204 Acrylic Emulsion waterborne emulsion coatings achieve both of these formerly exclusive properties: low microfoam entrapment and early print resistance. Note that the ambient conditions during evaluation were among the harshest encountered for waterborne coatings, 100°F (38°C) and 25% relative humidity.
  • Another benefit of RHOPLEXTM CL-204 Acrylic Emulsion is that the volatile organic content (VOC) of typically formulated clear topcoat lacquers is less than 2.5 pounds per gallon (less water) or 0.40 pounds of VOC per pound of polymer solids.

Applications & Uses

Properties

Physical Form
Characteristics of Coalescents
Chemical Type Commercial Designations Volatility BuAc = 100 Solubility, 20°C, Weight%
In Water Water In
Propylene Glycol n-Butyl Ether PNB 7 6.4 15.5
Ethylene Glycol Monobutyl Ether EB 6 Complete Complete
Dipropylene Glycol Methyl Ether DPM 2 Complete Complete
Dipropylene Glycol n-Butyl Ether DPnB 0.4 5 12
Diethylene Glycol Monobutyl
Ether
DB 0.3 Complete Complete
Ester Alcohol Texanol⁴ 0.2 Insoluble 0.9

4. Not recommended as a coalescent with Rhoplex CL-204 but included for comparison purposes.

Technical Details & Test Data

Technical Information
  • Viscosity - The viscosity of the CL-204-1 formulation will increase with pH adjustment as well as with the addition of coalescing aids. The use of ACRYSOL® RM-825 Rheology Modifier is recommended for further viscosity adjustment.
  • Flatting Agents - The below figure demonstrates the flatting efficiency of Degussa TS-100 matting agent or Syloid 7000 silica when added at 7% on emulsion solids. Either flatting agent can be used depending on the amount of gloss reduction desired. Coatings based on RHOPLEX® CL-204 Acrylic Emulsion maintain excellent clarity with both of these flatting agents.

RHOPLEX® CL-204 - Product Properties - 1

Gloss of RHOPLEX® CL-204 Acrylic Emulsion Coatings with Flatting Agents (7% on Emulsion Solids)

  • Wetting Agents - To prevent “picture framing” and improve wetting, use Surfynol 104 DPM surfactant at 0.5-1% on formulation solids. Wetting agent should be used sparingly because they can detract from the efficiency of RHOPLEX® CL-204 Acrylic Emulsion in preventing microfoam entrapment.
  • Defoamers - Tego Foamex 805 defoamer at 1-2% on polymer solids is recommended for use with RHOPLEX® CL-204 Acrylic Emulsion. For best results, add defoamers after coalescents and under good agitation.
  • Mar Aids - The addition of silicone-based mar aids will improve the slip and mar resistance of formulations based on RHOPLEX® CL-204 Acrylic Emulsion. Tego Glide 410 additive should be added at 1-2% solids on resin solids to impart mar and slip resistance. For best results, Tego Glide 410 additive should be reduced to 50% solids with an appropriate solvent (e.g., dipropylene glycol monomethyl ether) for ease of incorporation.
  • Waxes - Wax additives can impart mar, slip, and water resistance to the finished coating. Emulsified waxes with the smallest particle size are recommended for clarity. Powdered waxes impart haze to the finished coating due to their large particle size. Michemlube 39235 emulsion is recommended for use in RHOPLEX® CL-204 Acrylic Emulsion formulations.

Safety & Health

Safety Precautions
  • Keep combustible and/or flammable products and their vapors away from heat, sparks, flames and other sources of ignition including static discharge. Processing or operating at temperatures near or above product flashpoint may pose a fire hazard. Use appropriate grounding and bonding techniques to manage static discharge hazards.
  • Failure to maintain proper volume level when using immersion heaters can expose tank and solution to excessive heat resulting in a possible combustion hazard, particularly when plastic tanks are used.
  • Empty containers may contain hazardous residues. This material and its container must be disposed in a safe and legal manner.

 

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000005
Principal

Storage & Handling

Storage Conditions

Store products in tightly closed original containers at temperatures recommended on the product label.

Other

Appearance
Milky white liquid
Color (SDS)
White milky
Item Number
Odor (SDS)
Ammonia
Protect from Freezing
Yes
Temperature Control
Yes
USA/DOT UN Number
Not Applicable
Chemical Properties
ValueUnitsTest Method / Conditions
pH7.5-
Material Composition
ValueUnitsTest Method / Conditions
Solid Content43.0 %(W/W)%(W/W)
Volatile Organic Compounds (VOC)max. 3.0 g/Lg/L
Physical Properties
ValueUnitsTest Method / Conditions
Density8.65 lb/gallb/galwet
Density9.15 lb/gallb/galDry
Film Forming Temperature26.0 °C°C
Storage Temperature34.0-120.0 °F°F
Viscosity400.0 cPscPs
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Boiling Point (SDS)100.0 °C°C
Evaporation Rate (SDS)max. 1.0 %%Butyl acetate = 1
Melting Point (SDS)0.0 °C°C
Relative Vapor Density (SDS)max. 1.0-Air = 1
Specific Gravity (SDS)1.0-1.2-Water = 1
Vapor Pressure (SDS)17.0 mm Hgmm Hgat 20°C
Viscosity (SDS)100.0-500.0 mPa.smPa.s
Volatile Content (SDS)56.0-58.0 %%Water
pH (SDS)6.5-7.7-
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life0.0 dd