CYMEL® 1161

CYMEL® 1161 Resin is a highly monomeric, methylated/ iso-butylated melamine crosslinker with a high degree of alkylation. Its high monomer content allows for the formulation of high solids coatings with excellent appearance, recoat adhesion, and flexibility. CYMEL® 1161 Resin is especially recommended for automotive topcoats, general metal finishes, and coil coatings

Principal: allnex Crosslinkers

Functions: Crosslinking Agent

Chemical Family: Melamine Formaldehydes (MF)

Compatible Polymers & Resins: Acrylics, Alkyds, Epoxies (EP), Polyesters

End Uses: Primer, Solventless & High Solids Coating, Surface Coating, Top Coat

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Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Function
Crosslinking Agent
Product Code
MITM00224
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

Applications & Uses

Coating End Applications
Compatible Polymers & Resins
Markets
Applications
Formulation Stability
  • The stability of formulated systems containing CYMEL® 1161 Resin can be enhanced by the addition of primary alcohols, amines or a combination of these. Low molecular weight primary alcohols, such as ethanol and n-butanol, are most effective.
  • Recommended amines are DMEA or 2-AMP at a concentration of 0.5- 1.0% on total resin solids. Package stability can also be enhanced by the use of a blocked acid catalyst such as CYMEL® 4045 catalyst. For waterborne systems, pH should be adjusted between 7.5-8.5 to acheive optimum stability.

Properties

Technical Details & Test Data

Catalysis Information
  • Because of its high extent of alkylation, CYMEL® 1161 Resin responds best to sulfonic acid catalysts, like CYCAT® 4040 catalyst or CYCAT® 600 catalyst. Generally, 0.5 to 1.0% of CYCAT® 4040 catalyst on total resin solids of the formulation is sufficient to provide good cure at normal baking schedules (15-20 minutes at 120-150°C) in solvent-borne systems.
  • Water-borne systems generally require temperatures of 150°C or higher to effect cure. Higher concentrations of catalyst might be necessary if there are basic pigments or additives present in the formulation.
Backbone Polymer Selection
  • CYMEL® 1161 Resin contains mainly methoxymethyl and i-butoxymethyl functional sites making it a highly effective crosslinker for backbone polymer resins containing hydroxyl, carboxyl, or amide functional groups, such as those found on alkyd, polyester, or acrylic resins. Its high monomer content and low tendency to self-condense results in films with high flexibility and formability when paired with inherently flexible polymers, such as polyester resins.
  • The effective equivalent weight of CYMEL® 1161 typically ranges from 150-225, however, its optimum loading should be determined experimentally for each formulation with consideration of the performance properties to be optimized.

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions
  • CYMEL® 1161 Resin has a shelf life of 5 years from the date of manufacture when stored at temperatures between 5°C and 30°C. Although lower temperatures are not detrimental to stability, its viscosity will increase, possibly making the resin difficult to pump or pour.
  • The viscosity will reduce again on warming, but care should be taken to avoid excessive local heat, as this can cause an irreversible increase in viscosity

Other

Appearance
Clear liquid
Appearance (SDS)
Viscous liquid
Color (SDS)
Colorless
Item Number
Odor (SDS)
Slight formaldehyde
Other Hazards
Non Hazardous
USA/DOT UN Number
Not Applicable
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 40.0 APHAAPHA
Color Scalemax. 40.0 GardnerGardnerISO 6271
Chemical Properties
ValueUnitsTest Method / Conditions
Free Formaldehyde Contentmax. 0.15 %%Sulfite Method
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life5.0 yryr
Physical Properties
ValueUnitsTest Method / Conditions
Viscosity1000.0-1800.0 mPa.smPa.s
Material Composition
ValueUnitsTest Method / Conditions
Non-Volatile Contentmin. 98.0 %(W/W)%(W/W)at 45°C, foil, 45 min
Application Information
ValueUnitsTest Method / Conditions
Application pH7.5-8.5-
Dosage (Use Level)0.5-1.0 %%
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Density (SDS)1.1-1.3 g/cm³g/cm³
Flash Point (SDS)min. 93.0 °C°C