EBECRYL® 4250

EBECRYL® 4250 is an undiluted isocyanate functional urethane acrylate designed for use as an adhesion promoter in UV/EB coatings and in two component dual cure systems for coatings on wood, plastic and metal.

Principal: allnex Radcure

Functions: Adhesion Promoter, Coupling Agent

Chemical Family: Urethane Acrylates

End Uses: 1K (1 component) Coating, 2K (2 component) Coating, Polyurethane Coating, Primer, Radiation Curable Coating

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Enhanced TDS

Identification & Functionality

CASE Ingredients Functions
Chemical Family
Function
Adhesion Promoter, Coupling Agent
Product Code
MITM00312
Technologies
Product Families

Applications & Uses

Coating End Applications
Compatible Substrates & Surfaces
Cure Method
Markets
Applications
Product Applications

Formulations with EBECRYL 4250 can be used for;

  • Adhesion promotion in UV/EB curing coatings
  • UV/EB curable, two component polyurethane coatings
  • One component adhesion primer EBECRYL 4250 can be combined with hydroxyl functional resins to formulate coatings which cure by dual processes

UV/EB induced polymerization and NCO/OH reaction.  The product is also used in pure UV curing coatings to improve the adhesion on critical substrates as plastic, metal and exotic woods.  EBECRYL 4250 is suitable for the formulation of moisture-curing one-component polyurethane coatings, especially for one-component adhesion primers.

Formulation Information
  • The viscosity of EBECRYL 4250 can be reduced using standard reactive diluents such as dipropylene glycol diacrylate (DPGDA), 1,6-hexanediol diacrylate (HDDA), isobornyl acrylate (IBOA),and trimethylolpropane triacrylate (TMPTA) Suitable solvents are esters, ketones and aromatic hydrocarbons.
  • Reactive diluents and solvents containing reactive groups such as hydroxyl or amine groups strongly influence pot life and thus storage stability.
  • Coatings containing EBECRYL 4250 are applied by spray, curtain or roller coating at ≤ 100g/m² coat weight. After an adequate flash-off time of solvents (if any), the coatings are UV/EB cured. This creates a tack free and dust-dry surface. Following UV/EB curing, the post-reaction of NCO/OH groups takes place at room temperature or is forced. This results in good adhesion and good mechanical and chemical resistance of the coating.
  • EBECRYL 4250 has good compatibility with esters, ketones and aromatic hydrocarbons such as ethyl acetate, butyl acetate, methoxypropyl acetate, acetone, methyl ethyl ketone, methyl isobutyl ketone, xylene and mixtures thereof.
  • Only pure grade solvents should be used (max 0.05% water). EBECRYL 4250 should not be thinned below a non-volatile content of 40%. Prolonged storage of a solution with lower binder content may result in turbidity, sedimentation or even gelling.
  • Because of the many possible combinations with thinners and solvents, the compatibility and storage stability must be tested in each individual case.

Properties

Physical Form

Regulatory & Compliance

Certifications & Compliance
Contains any chemicals listed on Prop 65 (including impurities, residues, catalysts, monomers, and by-products and excluding heavy metals)?

Safety & Health

Safety Precautions

Avoid contact with eyes and skin. Direct contact with this material may cause skin irritation and serious eye irritation. Repeated skin contact may result in sensitization and cause an allergic skin reaction. Wash thoroughly after handling. Keep container tightly closed. Use with adequate ventilation.

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions

 The recommended storage temperature range for EBECRYL 4250 is 4°C to 40°C (39°F to 104°F). Care should be taken not to expose the product to high temperature conditions, direct sunlight, ignition sources, oxidizing agents, alkalis, acids or water. Prevent inadvertent contact with peroxides and other radical initiators and contact with copper, copper alloys, carbon steel, iron and rust. This might cause uncontrollable polymerization of the product with the generation of heat. Storage and handling should be in stainless steel, amber glass, amber polyethylene or baked phenolic lined containers. Procedures that remove or displace oxygen from the material should be avoided. Do not store this material under an oxygen free atmosphere. The product is sensitive to moisture. Skin formation may occur in opened containers. Dry air is recommended to displace material removed from the container.

Other

Appearance (SDS)
Liquid
Color (SDS)
Yellowish
Immiscible In (SDS)
Water
Item Number
Odor (SDS)
Ester like
Other Hazards
Polymerization may occur from excessive heat, contamination or exposure to direct sunlight .
USA/DOT UN Number
Not Applicable
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 100.0APHA
Physical Properties
ValueUnitsTest Method / Conditions
Density1.1g/mLAt 20°C
Flash Pointmin. 100.0°C
Viscosity2000.0mPa.sat 23°C
Material Composition
ValueUnitsTest Method / Conditions
Isocyanate Content5.0%
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Boiling Point (SDS)min. 200.0°CAt 1015 Hpa
Density (SDS)1.09g/cm³at 20°C
Flash Point (SDS)min. 200.0°CAt 1013 Hpa
Vapor Pressure (SDS)44.0hPaat 20°C
Viscosity (SDS)5567.0mPa.sAt 20°C