CYMEL® 350

CYMEL® 350 Resin is a highly methylated, monomeric melamine resin recommended for use in both waterborne and solvent-borne systems. It has very good water solubility properties, which makes it easy to incorporate with excellent stability in emulsion systems, as it remains in the water phase and does not migrate to the polymer phase. Like CYMEL® 350 Resin, it is a very efficient crosslinking agent and is recommended for coil coatings and high solids systems. CYMEL® 350 Resin has a slightly slower cure response than other monomeric methylated melamine resins. This provides excellent flow and levelling characteristics and less solvent popping on cure

Principal: allnex Crosslinkers

Functions: Crosslinking Agent

Chemical Family: Melamine Formaldehydes (MF)

Compatible Polymers & Resins: Acrylics, Alkyds, Epoxies (EP), Polyesters

End Uses: Solventless & High Solids Coating, Surface Coating, Waterborne Coating

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Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Function
Crosslinking Agent
Product Code
MITM00245
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

Applications & Uses

Coating End Applications
Compatible Polymers & Resins
Markets
Applications
Formulation Stability
  • The stability of formulated systems containing CYMEL® 350 Resin can be enhanced by the addition of primary alcohols, amines, or a combination of these. Low molecular weight primary alcohols, such as ethanol and n-butanol, are most effective.
  • Recommended amines are DMEA or 2-AMP at a concentration of 0.5-1.0% on total resin solids. Package stability can also be enhanced by the use of a blocked acid catalyst such as CYCAT 4045 catalyst. For waterborne systems, pH should be adjusted between 7.5-8.5 to achieve optimum stability.

Properties

Physical Form
Soluble In
Catalysis Information

Because of its high extent of alkylation, CYMEL® 350 Resin is quite stable and consequently will respond best to sulfonic acid catalysts, like CYCAT® 4040 catalyst or CYCAT® 600 catalyst. Generally, 0.5 to 1.0% of CYCAT® 4040 catalyst on total resin solids of the formulation is sufficient to provide good cure at normal baking schedules (15-20 minutes at 120-150°C) in solvent-borne systems. Water-borne systems generally require temperatures of 150°C or higher to effect cure. Higher concentrations of catalyst might be necessary if there are basic pigments or additives present in the formulation.

Backbone Polymer Selection
  • CYMEL® 350 Resin contains mainly methoxymethyl functionalities, making it a very effective crosslinker for backbone polymer resins containing hydroxyl, amide, or carboxyl functional groups, such as alkyd, polyester, or acrylic resins.
  • CYMEL® 350 Resin is highly compatible with a wide range of backbone polymers and provides films with very good hardness, flexibility, formability, adhesion, and resistance properties. Although the optimum level of CYMEL® 350 Resin in a given formulation should be determined experimentally, its effective equivalent weight will be typically in the range of 130-190.

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions
  • CYMEL® 350 Resin has a shelf life of 2 years from the date of manufacture when stored at temperatures between 5°C and 30°C. Although lower temperatures are not detrimental to stability, its viscosity will increase, possibly making the resin difficult to pump or pour.
  • The viscosity will reduce again on warming, but care should be taken to avoid excessive local heat, as this can cause an irreversible increase in viscosity.

Other

Appearance
Clear liquid
Appearance (SDS)
Viscous liquid
Color (SDS)
Clear
Item Number
Odor (SDS)
Slight formaldehyde
USA/DOT Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S.
USA/DOT Technical name (N.O.S.)
Formaldehyde
USA/DOT UN Number
UN3082
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 70.0 APHAAPHA
Color Scalemax. 70.0 GardnerGardnerISO 6271
Chemical Properties
ValueUnitsTest Method / Conditions
Free Formaldehyde Contentmax. 1.7 %%Sulfite Method
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life2.0 yryr
Physical Properties
ValueUnitsTest Method / Conditions
Viscosity5100.0-16000.0 cPscPsat 23°C, Cone & Plate
Material Composition
ValueUnitsTest Method / Conditions
Non-Volatile Contentmin. 97.0 %(W/W)%(W/W)at 45°C, foil, 45 min
Application Information
ValueUnitsTest Method / Conditions
Application pH7.5-8.5-
Dosage (Use Level)0.5-1.0 %%
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Density (SDS)1.1-1.3 g/cm³g/cm³
Flash Point (SDS)min. 93.0 °C°CSetaFlash Closed Cup
Volatile Content (SDS)max. 2.0 %%