EBECRYL® 4859

EBECRYL® 4859 is a difunctional aliphatic urethane methacrylate that does not contain any intentionally added organic tin compounds, heavy metals*, hydroquinone (HQ) or methyl ether of hydroquinone (MEHQ). (Please note that quinones are present in many raw materials, so the overall quinone content is reduced, but not zero in EBECRYL 4859.) Due to a low intrinsic viscosity, EBECRYL 4859 offers ease of formulating in energy curable systems that are low in viscosity with high oligomer content. Films of EBECRYL 4859 cured by ultraviolet light (UV) or electron beam (EB) exhibit good hardness, optically clarity, low color and good impact resistance.

Principal: allnex Radcure

Chemical Family: Urethane Methacrylates

End Uses: Screen Printing Ink, Wood Coating

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Enhanced TDS

Identification & Functionality

Blend
No
CAS Number
CASE Ingredients Functions
Chemical Family
Function
Monomer
Product Code
MITM10447
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

CASE Ingredients Features
Labeling Claims
Performance Highlights

EBECRYL® 4859 is characterized by:

  • No intentionally added tin, heavy metals, or quinones
  • Low viscosity
  • Light color

UV/EB cured products containing EBECRYL® 4859 are characterized by the following performance properties:

  • Regulation friendly for tin, heavy metals, and quinones
  • Abrasion resistance & Chemical resistance
  • Flexibility
  • Toughness & Impact resistance
  • Excellent outdoor durability

The actual properties of UV/EB cured products also depend on the selection of other formulation components such as reactive diluents, additives and photoinitiators. 

Applications & Uses

Application Method
Coating End Applications
Compatible Substrates & Surfaces
Cure Method
Ink & Toner End Applications
Markets
Applications
Product Applications

Formulated UV/EB curable products containing EBECRYL® 4859 may be applied via direct or reverse roll, offset gravure, metering rod, slot die, knife over roll, air knife, curtain, immersion and spin coating methods, as well as flexographic and screen printing. EBECRYL® 4859 is recommended for:

  • Applications that must meet regulations for tin, heavy metal, and quinone content
  • Ophthalmic lens casting
  • Coatings on rigid and flexible plastics
  • Use as a diluent for higher viscosity urethanes
  • Wood coatings
  • Screen inks

Properties

Physical Form

Regulatory & Compliance

Certifications & Compliance
Contains any chemicals listed on Prop 65 (including impurities, residues, catalysts, monomers, and by-products and excluding heavy metals)?

Technical Details & Test Data

Viscosity Reduction

Graph I - EBECRYL® 4859 - Viscosity reduction with reactive diluents

 

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Graph I shows the viscosity reduction of EBECRYL® 4859 with 1,6-hexanediol diacrylate (HDDA), isobornyl acrylate (IBOA), tripropylene glycol diacrylate (TPGDA) and trimethylolpropane triacrylate (TMPTA). Although viscosity reduction can be achieved with non-reactive solvents, reactive diluents are preferred because they are essentially 100 percent converted during UV/EB exposure to form a part of the coating or ink, thus reducing solvent emissions. The specific reactive diluents used will influence performance properties such as hardness and flexibility.

 

Graph II - EBECRYL® 4859 - Viscosity vs. Temperature

 

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Graph II illustrates the change in viscosity of EBECRYL® 4859 with increasing temperature.

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions

Care should be taken not to expose the product to high temperature conditions, direct sunlight, ignition sources, oxidizing agents, alkalis or acids. This might cause uncontrollable polymerization of the product with the generation of heat. Storage and handling should be in stainless steel, amber glass, amber polyethylene or baked phenolic lined containers. Procedures that remove or displace oxygen from the material should be avoided. Do not store this material under an oxygen free atmosphere. Dry air is recommended to displace material removed from the container. Wash thoroughly after handling. Keep container tightly closed. Use with adequate ventilation.

Other

Appearance
Clear liquid
Appearance (SDS)
Clear liquid
Color (SDS)
Clear colorless to light yellow
IATA/ICAO Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S. (acrylated resin)
IATA/ICAO UN Number
UN3082
IMO/IMDG Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S. (acrylated resin)
IMO/IMDG Technical name (N.O.S.)
acrylated resin
IMO/IMDG UN Number
UN3082
Item Number
Odor (SDS)
Ester
Other Hazards
Polymerization may occur from excessive heat, contamination or exposure to direct sunlight.
TDG Canada Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S. (acrylated resin)
TDG Canada Technical name (N.O.S.)
acrylated resin
TDG Canada UN Number
UN3082
USA/DOT Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S. (acrylated resin)
USA/DOT Technical name (N.O.S.)
acrylated resin
USA/DOT UN Number
UN3082
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 100.0 APHAAPHA
Mechanical Properties
ValueUnitsTest Method / Conditions
Elongation0.6 %%at break, UV cured 125 μ thick films
Elongation0.6 %%at break, UV cured, approx. 125μ thick films
Tensile Modulus393200.0 psipsiat break, UV cured 125 μ thick films
Tensile Modulus393200.0 psipsiUV cured 125 µ thick films
Tensile Strength2250.0 psipsiat break, UV cured 125 μ thick films
Tensile Strength2250.0 psipsiUV cured 125 µ thick films
Physical Properties
ValueUnitsTest Method / Conditions
Density1.14 g/mLg/mLAt 25°C
Glass Transition Temperature (Tg)124.0 °C°CDynamic Mechanical Analysis (DMA) at break, UV cured 125 μ thick films
Glass Transition Temperature (Tg)124.0 °C°CDynamic Mechanical Analysis (DMA) UV cured 125 µ thick films
Viscosity10000.0 cPscPsAt 25°C
Material Composition
ValueUnitsTest Method / Conditions
Oligomer Content100.0 %(W/W)%(W/W)
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Autoignition Temperature (SDS)425.0 °C°C
Boiling Point (SDS)min. 250.0 °C°C
Density (SDS)1.14 g/cm³g/cm³
Flash Point (SDS)196.0 °C°CCleveland Open Cup
Partition coefficient n-octanol/water (SDS)2.7-OECD 117 at 21°C, n-Octanol/Water
Solubility In Water (SDS)224.0 mg/Lmg/Lat 20°C
Vapor Pressure (SDS)0.7 PaPaat 20°C
Volatile Content (SDS)1.0 %%