EBECRYL® 8402

EBECRYL® 8402 is a low viscosity aliphatic urethane diacrylate. Films of EBECRYL® 8402 cured by ultraviolet light (UV) or electron beam (EB) exhibit good flexibility, toughness and excellent exterior durability. Low viscosity coatings or enhanced performance via increased oligomer content are possible with EBECRYL® 8402, Note that EBECRYL® 8402 typically develops a semi-crystalline aspect upon storage.

Principal: allnex Radcure

Chemical Family: Polyurethanes (PU), Urethane Diacrylate

End Uses: Flexography Ink, Radiation Curable Coating, Screen Printing Ink

Compatible Substrates & Surfaces: Vinyl, Wood

Features: Excellent Adhesion, Excellent Flexibility, Good Toughness, Low Viscosity, Non-Yellowing Grade, Outdoor Durability

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Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Function
Binder
Product Code
MITM00443
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

CASE Ingredients Features
Labeling Claims
Performance Highlights

EBECRYL®8402 is characterized by:

  • Low viscosity for handling ease
  • Light color

 

UV/EB cured products based on EBECRYL®8402 are characterized by the following performance properties:

  • Toughness
  • Flexibility
  • Exterior durability
  • Non-yellowing
  • Excellent adhesion to difficult substrates, particularly vinyl

The actual properties of UV/EB cured products also depend on the selection of other formulation components such as reactive diluents, additives and photoinitiators.

Applications & Uses

Application Method
Coating End Applications
Compatible Substrates & Surfaces
Cure Method
Ink & Toner End Applications
Markets
Applications
Product Application

Formulated UV/EB curable products containing EBECRYL®8402 may be applied via direct or reverse roll, offset gravure, metering rod, slot die, knife over roll, air knife, curtain, immersion and spin coating methods, as well as flexographic and screen printing.

 

EBECRYL®8402 is recommended for use in:

  • Coatings for wood
  • Coatings for plastics
  • Flexographic inks
  • Screen inks
  • Exterior durable coatings

Properties

Physical Form

Technical Details & Test Data

Viscosity Reduction

GRAPH I:EBECRYL®8402 - VISCOSITY REDUCTION WITH REACTIVE DILUENTS

EBECRYL®8402 - Viscosity Reduction - 1

GRAPH II:EBECRYL®8402 - VISCOSITY VS. TEMPERATURE

EBECRYL®8402 - Viscosity Reduction - 1

  • Graph I shows the viscosity reduction of EBECRYL®8402 with 1,6-hexanediol diacrylate (HDDA)¹, isobornyl acrylate (IBOA)¹, trimethylolpropane triacrylate (TMPTA)¹, and tripropylene glycol diacrylate (TPGDA)¹.
  • Although viscosity reduction can be achieved with non-reactive solvents, reactive diluents are preferred because they are essentially 100 percent converted during UV/EB exposure to form a part of the coating or ink, thus reducing solvent emissions.
  • The specific reactive diluents used will influence performance properties such as hardness and flexibility.
  • Graph II illustrates the change in viscosity of EBECRYL®8402 with increasing temperature.
  • ¹ Product of allnex

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage and Handling Conditions
  • Care should be taken not to expose the product to high temperature conditions, direct sunlight, ignition sources, oxidizing agents, alkalis or acids.
  • This might cause uncontrollable polymerization of the product with the generation of heat.
  • Storage and handling should be in stainless steel, amber glass, amber polyethylene or baked phenolic lined containers.
  • Procedures that remove or displace oxygen from the material should be avoided.
  • Do not store this material under an oxygen free atmosphere.
  • Dry air is recommended to displace material removed from the container.
  • Wash thoroughly after handling.
  • Keep container tightly closed. Use with adequate ventilation.
  • Upon storage, EBECRYL®8402 may show signs of crystallization.
  • This crystallization can be removed by heating containers of EBECRYL®8402 to a uniform temperature of 60°C.
  • Ovens or hotboxes are recommended methods of heating.
  • Heating tapes should not be used. In typical formulations, EBECRYL®8402 does not exhibit signs of crystallization.

Other

Appearance
Clear liquid
Appearance (SDS)
Clear to slightly hazy liquid
Color (SDS)
Clear colorless to light straw
Insoluble in (SDS)
Water
Item Number
Odor (SDS)
Acrylate
Other Hazards
Polymerization may occur from excessive heat ,contamination or exposure to direct sunlight , Contact with skin may cause a cross-allergic reaction in persons already sensitized to acrylates.
USA/DOT UN Number
Not Applicable
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 1.0 GardnerGardnerGardner Color Scale
Mechanical Properties
ValueUnitsTest Method / Conditions
Elongation50.0 %%at break, UV cured 125 μ thick films
Tensile Modulus97.0 MPaMPaat break, UV cured 125 μ thick films
Tensile Modulus14000.0 psipsiUV cured 125 µ thick films
Tensile Strength23.0 MPaMPaat break, UV cured 125 μ thick films
Tensile Strength3350.0 psipsiUV cured 125 µ thick films
Physical Properties
ValueUnitsTest Method / Conditions
Density1.12 g/mLg/mLAt 25°C
Glass Transition Temperature (Tg)14.0 °C°CDynamic Mechanical Analysis (DMA) at break, UV cured 125 μ thick films
Glass Transition Temperature (Tg)14.0 °C°CDynamic Mechanical Analysis (DMA) UV cured 125 µ thick films
Viscosity15000.0 mPa.smPa.sAt 25°C
Viscosity450.0-650.0 mPa.smPa.sat 65.5°C
Material Composition
ValueUnitsTest Method / Conditions
Oligomer Content100.0 %(W/W)%(W/W)
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Boiling Point (SDS)min. 100.0 °C°C
Density (SDS)1.13 g/cm³g/cm³
Flash Point (SDS)220.0 °C°C
Vapor Pressure (SDS)0.013 hPahPaat 20°C
Volatile Content (SDS)max. 0.5 %%