RHOPLEX® PR-33

RHOPLEX® PR-33 is an aqueous, all-acrylic, binder designed for exterior and interior primers and stain blocking sealers. This binder uses ambient cross linking technology to offer improved primer performance versus conventional latex polymers. The combination of an all-acrylic backbone and ambient cure crosslinking technology contribute to the excellent balance of properties found with RHOPLEX® PR-33 Emulsion Polymer. The excellent film formation achieved blocks stains from migrating through the dry paint film and yields stain blocking performance at high PVC. Enhanced adhesion and excellent durability are additional attributes of this technology.

Principal: Dow Coating Materials

Functions: Binder & Resin, Crosslinking Agent

Chemical Family: Chemical Mixtures & Blends

Compatible Substrates & Surfaces: Cedar, Paper, Pine Wood, Redwood, Wood

End Uses: Clearcoat, DTM Coating, Opaque Stain, Paper Coating, Pigmented Coating, Primer, Sealer, Wood Coating

Labeling Claims: Not Listed In California Proposition 65

Features: Color Retention, Crack Resistance, Dirt Pickup Resistance, Excellent Adhesion, Excellent Film Properties, Excellent Formulation Flexibility, Excellent Stain Blocking, Flash Rust Resistance, Good Zinc Oxide Stability, High Durability, Nail Head Rust Resistance, Outdoor Durability, Self Crosslinking, Stain Resistance, UV Resistance, Wood Tannin Blocking

Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Country of Origin
Function
Binder & Resin, Crosslinking Agent
Product Code
MITM11253
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

CASE Ingredients Features
Labeling Claims
Product Benefits
  • 100% acrylic composition
  • Unique ambient crosslinking technology provides:
  • Excellent tannin, marker, water, and nicotine stain blocking
  • Enhanced adhesion to a variety of repaint and new substrates
  • Wide formulation latitude provides performance at high PVC
  • Excellent flash rust and nail head rust resistance
  • Excellent exterior crack resistance over dimensionally unstable substrates and weathered wood
  • Good zinc oxide stability
  • Low VOC

Applications & Uses

Properties

Physical Form

Technical Details & Test Data

Technical Data

Exterior Durability
With over five years of exterior exposure data, the all-acrylic composition ofRHOPLEX® PR-33 Emulsion Polymer provides excellent exterior durability in primer formulations.
Figure 1 shows the outstanding crack resistance, over weathered white pine, of a primer based on RHOPLEX® PR-33 Emulsion Polymer.

Crack Resistance of Primers on 3-Month Weathered White Pine Exposed at South 45

RHOPLEX® PR-33 - Technical Data - 1

Exterior Resistance Properties
Table 1 displays the excellent exterior tannin stain blocking, rust resistance and blistering characteristics of RHOPLEX® PR-33 Emulsion Polymer versus a competitive latex vehicle and a self-primed topcoat.

Table 1: Exterior Performance Comparison of Partners 6 Months Exposure (00AJ)

  RHOPLEX®; PR-33 Emulsion
Polymer
Primer 31PVC/35VS
Competitive Latex Primer
31PVC/35VS

Self Primed Topcoat

Tannin Stain Blocking 8 6 3
Nail Head Rust Resistance 9 6 4
Rust Staining Cold Rolled Steel 10 8 1
Blistering on Unspangled Galvanized 10 1 5

Enhanced Adhesion
Figure 2 shows the enhanced wet adhesion of RHOPLEX® PR-33 Emulsion Polymer, over a variety of substrates, compared to a conventional acrylic primer. The primers were tested in a 31 PVC/35 VS formulation after one week dry at 25°C and 50% RH. The primers were placed in a streaming fog box for five hours prior to testing.

Figure 2: Wet Adhesion of RHOPLEX® PR-33 Emulsion Polymer

RHOPLEX® PR-33 - Technical Data - 1

Another area where RHOPLEX® PR-33 Emulsion Polymer excels in stain blocking performance is over many common household stains.
Table 3 shows the comparative stain blocking performance of RHOPLEX® PR-33 Emulsion Polymer over a variety of difficult household stains. These stains include nicotine, water, tannin, grape juice, coffee and lipstick.

Household Stain Blocking Performance

Stain Type RHOPLEX® PR-33 Emulsion
Polymer
Primer 31PVC/35VS
Competitive Latex Primer
31PVC/35VS

RHOPLEX® PR-3232LO Primer
31PVC/35VS

Nicotine Stained Vinyl Chart¹ 8 6 7
Water Damaged Ceiling Tile² 6 4 6
Tannin Stain Block Cedar³ 8 5 6
Tannin Stain Block Redwood³ 6 3 4
Grape Juice¹ 8 7 7
Coffee¹ 6 5 5
Lipstick¹ 9 8 7

Ratings: 10 = Best, no visible stain 0 = Complete bleen through
¹ One coat of primer applied via drawdown and allowed to dry 2 hours. One application of flat PVA topcoat.
² Two coats of respective primer and one application of flat PVA topcoat. One hour to dry between coats.
³ Primer applied at 350 ft²/gal., dry 4 hours, topcoat with G-08-2 exterior acrylic semigloss.

Safety & Health

Safety Precautions

Based on similar materials, this product is not expected to be toxic via single acute oral or dermal exposure. It may be a mild to moderate skin and eye irritant.

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000005
Principal

Other

Appearance
Milky white liquid
Color (SDS)
Light yellow
Item Number
Odor (SDS)
Ammonia
Protect from Freezing
Yes
Temperature Control
Yes
USA/DOT UN Number
Not Applicable
Chemical Properties
ValueUnitsTest Method / Conditions
pH8.5-9.5-
Material Composition
ValueUnitsTest Method / Conditions
Solid Content43.0 %%
Physical Properties
ValueUnitsTest Method / Conditions
Bulking Value0.1037 gal/lbgal/lbdry solids
Bulking Value0.113 gal/lbgal/lbwet
Density8.85 g/cm³g/cm³
Film Forming Temperature6.0 °C°C
Storage Temperature34.0-120.0 °F°F
Viscosity50.0-1000.0 cPscPsBrookfield Viscometer
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Boiling Point (SDS)100.0 °C°C
Evaporation Rate (SDS)max. 1.0 %%
Melting Point (SDS)0.0 °C°C
Relative Vapor Density (SDS)max. 1.0-
Specific Gravity (SDS)1.0-1.2-
Vapor Pressure (SDS)17.0 mm Hgmm Hgat 20°C
Viscosity (SDS)10.0-300.0 mPa.smPa.s
Volatile Content (SDS)55.0-58.0 %%
pH (SDS)8.5-9.5-
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life540.0 dd