CRAYVALLAC® PA3 X 20

Principal: Arkema Rheology and Specialty Additives Group

Functions: Rheology Modifier

Chemical Family: Amide Waxes

End Uses: Solventborne Coating, Top Coat, Varnishes, Wood Coating

Compatible Polymers & Resins: Acrylics, Alkyds, Nitrocellulose, Polyurethanes (PU)

Physical Form: Paste

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Identification & Functionality

CASE Ingredients Functions
Carrier
Chemical Family
Function
Rheology Modifier
Product Code
MITM01580
Technologies
Product Families

Features & Benefits

CASE Ingredients Features
Product Benefits
  • CRAYVALLAC® PA3 X 20 is a pre-activated amide wax dispersed in a mixture of xylene and alcohols.
  • It is a rheology modifier in paste form for post-addition to solvent-based industrial coatings and industrial wood finishes.

The use of CRAYVALLAC® PA3 X 20 provides a very simple and direct means of introducing shear-thinning rheology with thixotropic viscosity recovery to coating formulations. Solvent-based industrial coatings:

  • CRAYVALLAC® PA3 X 20 is particularly recommended for clear varnishes and topcoats where a high gloss is important.
  • Suitable for post-addition
  • Easy to incorporate
  • Imparts shear-thinning rheology with thixotropic viscosity recovery
  • Very good sag resistance
  • Very good anti-settle properties
  • Good recoatability Industrial wood finishes:
  • CRAYVALLAC® PA3 X 20 can be used in a variety of industrial wood finishes e.g. polyurethane (alkyd or acrylic based), nitrocellulose and acid curing.
  • It is particularly suited to applications where strong anti-sag and anti-settle properties are required e.g. sealers.

The performance benefits of this product in industrial wood finishes are:

  1. Post-addition rheology modifier
  2. Suitable for higher build coatings
  3. No pre-gel preparation required
  4. Imparts shear-thinning rheology with thixotropic viscosity recovery
  5. Excellent pigment and filler suspension during storage
  6. Coating formulations that are easy to apply yet exhibit excellent sag resistance combined with very good flow and levelling
  7. Prevention of excessive substrate penetration with clear sealers and consequently improvement of filling power and coverage In addition to these excellent performance benefits, CRAYVALLAC® PA3 X 20 is also a very cost efficient alternative to organoclays.
  • CRAYVALLAC® PA3 X 20 is a pre-activated amide paste and exists in the form of crystalline fibres.
  • In a coating system, these fibres form an interacting network. It is this fibrous network that gives rise to the shear-thinning rheology of the final coating.
  • This shear-thinning characteristic provides a very high viscosity under the low shear rates associated with sedimentation, and a low viscosity at the much higher application shear rates.
  • The net result is excellent control of sedimentation combined with ease of application.
  •  Immediately following application, where low shear conditions again predominate, the coating’s viscosity undergoes a time dependent recovery as the network re- establishes itself. This time dependence is known as thixotropy and enables the final coating to attain very good levelling.
  • In order to obtain maximum efficiency from CRAYVALLAC® PA3 X 20, it is necessary to disperse this product without destroying the crystalline fibres.
  • It is therefore preferable to incorporate CRAYVALLAC® PA3 X 20 under low to medium shear conditions over as short a time period as possible.
  • There are two main methods by which CRAYVALLAC® PA3 X 20 can be incorporated:
  • Post addition: When using a high-speed disperser, CRAYVALLAC® PA3 X 20 is added during the final stages of production, when the coating has been partially thinned to a viscosity of 600-800mPas (ICI cone and plate at 10000s-¹) and the peripheral speed reduced to approximately 4ms-¹.
  • Too high a speed will result in destruction of the active fibres and reduced performance, whereas, too low a speed will result in extended incorporation times.
  • In general, the time required for incorporation should be kept to a minimum in order to minimise damage due to overshear.
  • Master batch preparation: A master batch can be prepared by dispersing CRAYVALLAC® PA3 X 20 in a resin and/or solvent using low to medium shear rates.
  • This dispersion can then be added to the finished coating
  • Due to the multitude of formulations, processing methods and application conditions used in the field, we strongly recommend that all products containing CRAYVALLAC® PA3 X 20 be tested thoroughly to ensure suitability for their intended end use.
  • In particular, the suitability of this product for application by hot- spray, or curing in poorly ventilated areas may require additional validation.
  • We do not recommend CRAYVALLAC® PA3 X 20 for forced cure and stoving applications.

Applications & Uses

Properties

Physical Form

Packaging & Availability

Packaging Type

Storage & Handling

Storage Conditions
  • Use corrosion- resistant storage tanks and piping.
  • Air-operated diaphragm pumps are preferred.
  • Avoid temperature extremes.
  • Do not freeze; store between 5°- 30°C.
  • Under these conditions the product may be stored for up to 24 months from production date.

Other

Appearance
Off white paste
Burning Rate (SDS)
20.0 mm/s
Color (SDS)
Off-white
Density
0.88 g/cm³
Density (SDS)
0.86 g/cm³
Dosage (Use Level)
0.5-2.0 %
Dosage (Use Level)
2.0-5.0 %
Flash Point (SDS)
68.0 °F
Group Principal Number
S000003
IMO/IMDG Proper Shipping Name
Solids containing flammable liquid, N.O.S. (xylene, ethanol)
IMO/IMDG Technical name (N.O.S.)
Xylene, Ethanol
IMO/IMDG UN Number
UN3175
Insoluble in (SDS)
Water
Item Number
Non-Volatile Content
19.0-21.0 %
Odor (SDS)
Sweet, oily
Other Hazards
Dried product may stick to the skin causing irritation upon removal.
Principal
Shelf Life
24.0 mo
Specific Gravity (SDS)
0.86
Storage Temperature
41.0-86.0 °F
USA/DOT Proper Shipping Name
Solids containing flammable liquid, N.O.S. (xylene, ethanol)
USA/DOT Technical name (N.O.S.)
Xylene, Ethanol
USA/DOT UN Number
UN3175
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life24.0 momo
Physical Properties
ValueUnitsTest Method / Conditions
Density0.88 g/cm³g/cm³CR 006
Storage Temperature41.0-86.0 °F°F
Material Composition
ValueUnitsTest Method / Conditions
Non-Volatile Content19.0-21.0 %%Internal Method at 150°C
Application Information
ValueUnitsTest Method / Conditions
Dosage (Use Level)0.5-2.0 %%anti-Settling
Dosage (Use Level)2.0-5.0 %%
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Burning Rate (SDS)20.0 mm/smm/sWetted Zone Does Not Stop Fire
Density (SDS)0.86 g/cm³g/cm³at 20°C
Flash Point (SDS)68.0 °F°FSetaFlash Closed Cup
Specific Gravity (SDS)0.86-at 20°C, water = 1