Dynasylan® 1122

Dynasylan® 1122 is a secondary aminofunctional ethoxysilane possessing two symmetric silicone atoms. Dynasylan® 1122 acts as an adhesion promoter between inorganic materials (for example glass, metals and fillers) and organic polymers (thermosets, thermoplastics and elastomers), as a surface modifier and can be used for the chemical modification of substances. Dynasylan® 1122 is a colorless to yellow liquid with an amine- like odor which is, for example, soluble in alcohols, aliphatic or aromatic hydrocarbons.

Principal: Evonik Corporation Silanes

Functions: Adhesion Promoter, Adhesion Promoter, Crosslinking Agent, Sizing Agent, Surface Modifier, Surface Modifier

RTU Product Type: Primer

Chemical Family: Amines

Compatible Polymers & Resins: Epoxies (EP), Ethylene Vinyl Acetate (EVA), Furans, Melamines & Melamine Formaldehydes (MF), Phenolics, Polyamides, Polybutylene Terephthalate (PBT), Polycarbonates (PC), Polypropylenes (PP), Polyurethanes (PU), Polyvinyl Acetate (PVA), Polyvinyl Butyral (PVB), Polyvinyl Chloride (PVC), Silicones

Compatible Substrates & Surfaces: Aluminum, Cristobalite, Glass, Glass Fiber, Glass Wool, Kaolin, Metal, Mica, Mineral Wool, Quartz, Sand, Wollastonite

Applicable Processes: Abrasives Manufacturing, Filler Pre-Treatment, Pigment Pre-Treatment

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Enhanced TDS

Identification & Functionality

Features & Benefits

Applications & Uses

Applicable Processes
Compatible Polymers & Resins
Compatible Substrates & Surfaces
Industrial Additives End Use
Plastics & Elastomers End Uses
Markets
Applications
Product Applications

Dynasylan® 1122 is an important additive in many applications.
Examples are:

  • Glass fiber/glass fabric composites: as size constituent or finish
  • Metal primers
  • Mineral fiber insulating materials, abrasives: as additive to phenolic resin binders
  • Foundry resins: as additive to phenolic, furane and melamine resins
  • Adhesives and sealants: as primer or additive
  • Mineral­filled polymers (composites) or HFFR cables: for pretreatment of fillers and pigments
  • Paints and coatings: as additive and primer for improving adhesion to the substrate

The most important effects which can be achieved using Dynasylan® 1122 are:
Improvement in product properties, such as

  • Flexural strength, tensile strength, impact strength and
  • modulus of elasticity
  • Moisture and corrosion resistance
  • improvement in processing properties, such as
  • Adhesion
  • Filler dispersion
  • Rheological behavior: reduction in viscosity, Newtonian behavior
  • Higher degree of filling
Processing Information
  • Dynasylan® 1122 can advantageously be employed in organic solvents, as constituent of aqueous sizes, as pure substance or added to the polymer as an additive.
  • In higher concentrations (1-­5 wt.­%) chemical modification can be achieved by reaction with suitable functional monomers or polymers, for example those containing epoxy groups.

Properties

Physical Form
Soluble In
Product Reactivity
  • Dynasylan® 1122 is a bifunctional organic compound in which the silicon­functional ethoxy­groups hydrolyze in the presence of water to form reactive silanols, which can be bonded to an inorganic substrate; the organophilic amino group can interact with a suitable polymer.
  • Due to 6 hydrolyzable substituents present in one molecule, Dynasylan® 1122 is exceptionally suitable to form highly crosslinked networks on and between substrates and in organic matrices.
  • The hydrolysis of Dynasylan® 1122 in water takes place by acidic catalysis (e.g. formic or acetic acid at a pH of 2­3).
  • In order to achieve solubility in organic solvents simply add 2­4 wt.­% of water per wt.­% of Dynasylan® 1122.
  • Upon stirring for 5h the solutions are ready for use.
  • Examples of suitable inorganic substrates are glass, glass fibers, glass wool, mineral wool, silicic acid, quartz, sand, cristobalite, wollastonite and mica; also suitable are aluminum hydroxide, kaolin, talc, other silicate fillers, metal oxides and metals.
  • Examples of suitable polymers are epoxy resins, polyurethanes, phenolic resins, furan resins, melamine resins, PA, PBT, PC, EVA, modified PP, PVB, PVAC, PVC, acrylates and silicones.
  • The secondary amino group in Dynasylan® 1122 provides high basicity at somewhat lower reactivity compared to primary amino groups.
  • This is of major advantage in e.g. adhesives and sealants where the silane is added to the polymer matrix:
  • Homogeneous distribution and bonding/networking of Dynasylan® 1122 to the inorganic filler can commence unless bonding to organic materials (e.g. polymers) will proceed. Moreover, Dynasylan® 1122 has been successfully used as a component in aqueous PA­ and PU­sizes for glass fibers.

Regulatory & Compliance

Packaging & Availability

Packaging Type
Product Packaging
  • Dynasylan® 1122 is supplied in convenient small sized package (25 kg) and in 180 kg drums.
  • In the originally closed drums

Storage & Handling

Storage Conditions
  • Dynasylan® 1122 has a shelf life of at least of 12 months.

Other

Appearance
colorless to yellow liquid
Autoignition Temperature (SDS)
255.0 °C
Boiling Point
min. 300.0 °C
Boiling Point (SDS)
min. 300.0 °C
Color (SDS)
Yellowish
Density
0.97 g/cm³
Density (SDS)
0.97 g/cm³
Flash Point (SDS)
95.0 °C
Flash Point (SDS)
min. 140.0 °C
Immiscible In (SDS)
Water
Item Number
Melting Point (SDS)
max. -38.0 °C
Odor
Amine ­like odor
Odor (SDS)
Amine like
Principal
Shelf Life
12.0 mo
Vapor Pressure (SDS)
max. 0.01 hPa
Viscosity
5.5 mPa.s
Viscosity (SDS)
5.5 mPa.s
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life12.0 momo
Physical Properties
ValueUnitsTest Method / Conditions
Boiling Pointmin. 300.0 °C°CASTM D1120 At 1013 Hpa
Density0.97 g/cm³g/cm³DIN 51757 At 20°C
Viscosity5.5 mPa.smPa.sDIN 53015 At 20°C
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Autoignition Temperature (SDS)255.0 °C°C
Boiling Point (SDS)min. 300.0 °C°CASTM D1120 At 1013 Hpa
Density (SDS)0.97 g/cm³g/cm³DIN 51757 at 20°C
Flash Point (SDS)95.0 °C°CEC Method A9
Flash Point (SDS)min. 140.0 °C°CISO 2592
Melting Point (SDS)max. -38.0 °C°C
Vapor Pressure (SDS)max. 0.01 hPahPaASTM D2879-86 at 20°C
Viscosity (SDS)5.5 mPa.smPa.sDIN 53015 at 20°C