Dynasylan® 1122

Dynasylan® 1122 is a secondary aminofunctional ethoxysilane possessing two symmetric silicone atoms. Dynasylan® 1122 acts as an adhesion promoter between inorganic materials (for example glass, metals and fillers) and organic polymers (thermosets, thermoplastics and elastomers), as a surface modifier and can be used for the chemical modification of substances. Dynasylan® 1122 is a colorless to yellow liquid with an amine- like odor which is, for example, soluble in alcohols, aliphatic or aromatic hydrocarbons.

Principal: Evonik Corporation Silanes

Functions: Adhesion Promoter, Crosslinking Agent, Reagent, Sizing Agent, Surface Modifier

RTU Product Type: Primer

Chemical Family: Amines, Organosilane

End Uses: Abrasives, Cables, Filler Pre-Treatment, Foundry Resins, Joinery, Pigment Pre-Treatment, Solventborne Adhesive, Woodwork

Labeling Claims: Not Listed In California Proposition 65

Features: Controlled Viscosity, Corrosion Resistance, Excellent Mineral Filler Loading Capability, Good Adhesion Property, Good Impact Strength, Good Moisture Resistance, High Filler Loading, High Impact Strength, High Modulus of Elasticity, High Tensile Strength, Improved Flexural Strength, Improves Filler Dispersibility, Increased Tensile Strength, Increases Flexural Modulus, Moisture Resistance, Reduces Viscosity

Enhanced TDS

Identification & Functionality

Features & Benefits

Applications & Uses

Product End Uses
Markets
Applications
Product Applications

Dynasylan® 1122 is an important additive in many applications.
Examples are:

  • Glass fiber/glass fabric composites: as size constituent or finish
  • Metal primers
  • Mineral fiber insulating materials, abrasives: as additive to phenolic resin binders
  • Foundry resins: as additive to phenolic, furane and melamine resins
  • Adhesives and sealants: as primer or additive
  • Mineral­filled polymers (composites) or HFFR cables: for pretreatment of fillers and pigments
  • Paints and coatings: as additive and primer for improving adhesion to the substrate

The most important effects which can be achieved using Dynasylan® 1122 are:
Improvement in product properties, such as

  • Flexural strength, tensile strength, impact strength and
  • modulus of elasticity
  • Moisture and corrosion resistance
  • improvement in processing properties, such as
  • Adhesion
  • Filler dispersion
  • Rheological behavior: reduction in viscosity, Newtonian behavior
  • Higher degree of filling
Processing Information
  • Dynasylan® 1122 can advantageously be employed in organic solvents, as constituent of aqueous sizes, as pure substance or added to the polymer as an additive.
  • In higher concentrations (1-­5 wt.­%) chemical modification can be achieved by reaction with suitable functional monomers or polymers, for example those containing epoxy groups.

Properties

Physical Form
Soluble In
Product Reactivity
  • Dynasylan® 1122 is a bifunctional organic compound in which the silicon­functional ethoxy­groups hydrolyze in the presence of water to form reactive silanols, which can be bonded to an inorganic substrate; the organophilic amino group can interact with a suitable polymer.
  • Due to 6 hydrolyzable substituents present in one molecule, Dynasylan® 1122 is exceptionally suitable to form highly crosslinked networks on and between substrates and in organic matrices.
  • The hydrolysis of Dynasylan® 1122 in water takes place by acidic catalysis (e.g. formic or acetic acid at a pH of 2­3).
  • In order to achieve solubility in organic solvents simply add 2­4 wt.­% of water per wt.­% of Dynasylan® 1122.
  • Upon stirring for 5h the solutions are ready for use.
  • Examples of suitable inorganic substrates are glass, glass fibers, glass wool, mineral wool, silicic acid, quartz, sand, cristobalite, wollastonite and mica; also suitable are aluminum hydroxide, kaolin, talc, other silicate fillers, metal oxides and metals.
  • Examples of suitable polymers are epoxy resins, polyurethanes, phenolic resins, furan resins, melamine resins, PA, PBT, PC, EVA, modified PP, PVB, PVAC, PVC, acrylates and silicones.
  • The secondary amino group in Dynasylan® 1122 provides high basicity at somewhat lower reactivity compared to primary amino groups.
  • This is of major advantage in e.g. adhesives and sealants where the silane is added to the polymer matrix:
  • Homogeneous distribution and bonding/networking of Dynasylan® 1122 to the inorganic filler can commence unless bonding to organic materials (e.g. polymers) will proceed. Moreover, Dynasylan® 1122 has been successfully used as a component in aqueous PA­ and PU­sizes for glass fibers.

Regulatory & Compliance

Manufacturing Facility Standards

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000006
Principal

Storage & Handling

Storage Conditions
  • Dynasylan® 1122 has a shelf life of at least of 12 months.

Other

Appearance
colorless to yellow liquid
Color (SDS)
Yellowish
Immiscible In (SDS)
Water
Item Number
Material Compatibility
Odor
Amine ­like odor
Odor (SDS)
Amine like
Protect from Freezing
No
Temperature Control
No
USA/DOT UN Number
Not Applicable
Physical Properties
ValueUnitsTest Method / Conditions
Boiling Pointmin. 300.0°CASTM D1120 at 101.3kPa
Density0.97g/cm³DIN 51757 at 20°C
Viscosity5.5mPa.sDIN 53015 at 20°C
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Autoignition Temperature (SDS)255.0°C
Boiling Point (SDS)min. 300.0°CASTM D1120 at 101.3kPa
Density (SDS)0.97g/cm³DIN 51757 at 20°C
Flash Point (SDS)95.0°CEC Method A9
Flash Point (SDS)min. 140.0°CISO 2592
Melting Point (SDS)max. -38.0°C
Vapor Pressure (SDS)max. 0.01hPaASTM D2879 at 20°C
Viscosity (SDS)5.5mPa.sDIN 53015 at 20°C
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life12.0mo