EBECRYL® 4397

EBECRYL® 4397 is an undiluted isocyanate aliphatic functional urethane acrylate designed for use in UV/EB coatings and in two component dual cure systems for coatings on wood, plastic and metal. EBECRYL® 4397 exhibits greater flexibility in comparison to other isocyanate functional urethane acrylates such as EBECRYL 4150(1).

Principal: allnex Radcure

Chemical Family: Polyurethanes (PU), Urethane Acrylates

End Uses: 1K (1 Component) Primer, 2K (2 component) Coating, Polyurethane Coating, Radiation Curable Coating

Compatible Substrates & Surfaces: Metal, Plastics, Wood

Features: Improved Flexibility

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Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Function
Binder
Product Code
MITM11127
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

CASE Ingredients Features

Applications & Uses

Application Method
Coating End Applications
Compatible Substrates & Surfaces
Cure Method
Markets
Applications
Product Applications

Formulations with EBECRYL® 4397 can be used for;

  • UV/EB curable, two component polyurethane coatings
  • One component adhesion primer

EBECRYL® 4397 can be combined with hydroxyl functional resins to formulate coatings which cure by dual processes; UV/EB induced polymerization and NCO/OH reaction.
The product is also used in straight UV/EB curing coatings to improve the adhesion on substrates such as plastic, metal and exotic woods.

Formulation Information
  • The viscosity of EBECRYL® 4397 can be reduced using standard reactive diluents such as dipropylene glycol diacrylate (DPGDA), 1,6-hexanediol diacrylate (HDDA)(1), isobornyl acrylate (IBOA), and trimethylolpropane triacrylate (TMPTA), and non-reactive solvents.
  • Suitable solvents are esters, ketones and aromatic hydrocarbons.Non-reactive solvents must be evaporated prior to curing. Only pure grade solvents should be used (max 0.05% water).
  • EBECRYL® 4397 should not be thinned below a non-volatile content of 40%.
  • Prolonged storage of a solution with lower binder content may result in turbidity, sedimentation or even gelling.
  • Reactive diluents and solvents containing reactive groups such as hydroxyl or amine groups strongly influence pot life and storage stability.
  • Coatings containing EBECRYL® 4397 may be applied by spraying, curtain or roller coated at ≤ 100g/m² coat weight.
  • After an adequate flash-off time of solvents (if any), the coatings are UV/EB cured. This creates a tack free and dust-dry surface.
  • Following UV/EB curing, any post-reaction of NCO/OH groups takes place at room temperature or is forced by heat.
  • This results in good adhesion and good mechanical and chemical resistance of the coating.
  • EBECRYL® 4397 has good compatibility with esters, ketones and aromatic hydrocarbons such as ethyl acetate, butyl acetate, methoxypropyl acetate, acetone, methyl ethyl ketone, methyl isobutyl ketone, xylene and mixtures thereof.
  • Because of the many possible combinations with thinners and solvents, the compatibility and storage stability should be tested in each individual case.

Properties

Physical Form

Regulatory & Compliance

Certifications & Compliance
Contains any chemicals listed on Prop 65 (including impurities, residues, catalysts, monomers, and by-products and excluding heavy metals)?

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions
  • Care should be taken not to expose the product to high temperature conditions, direct sunlight, ignition sources, oxidizing agents, alkalis or acids.
  • This might cause uncontrollable polymerization of the product with the generation of heat.
  • Storage and handling should be in stainless steel, amber glass, amber polyethylene or baked phenolic lined containers.
  • Procedures that remove or displace oxygen from the material should be avoided.
  • Do not store this material under an oxygen free atmosphere.
  • Dry air is recommended to displace material removed from the container.
  • Wash thoroughly after handling.
  • Keep container tightly closed.
  • Use with adequate ventilation.

Other

ADR/RID/ADN Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S.
ADR/RID/ADN UN Number
UN3082
Appearance (SDS)
Liquid
Color (SDS)
Yellowish
Immiscible In (SDS)
Water
Odor (SDS)
Odorless
Other Hazards
Polymerization may occur from excessive heat ,contamination or exposure to direct sunlight. Caution -Substance not yet fully tested . For research and development purposes only .
USA/DOT Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S.
USA/DOT Technical name (N.O.S.)
Hexamethylene diisocyanate
USA/DOT UN Number
UN3082
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 150.0APHA
Color Scalemax. 150.0HazenHazen Color Scale
Physical Properties
ValueUnitsTest Method / Conditions
Density1.1g/mLAt 20°C
Flash Pointmin. 100.0°C
Viscosity11000.0mPa.sAt 25°C
Material Composition
ValueUnitsTest Method / Conditions
Isocyanate Content6.7%
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Boiling Point (SDS)min. 300.0°CAt 1.013 Hpa
Density (SDS)1.13g/cm³DIN 51757
Flash Point (SDS)min. 240.0°CDIN EN ISO 2719
Vapor Pressure (SDS)43.0hPaInternal Method at 20°C
Viscosity (SDS)12500.0mPa.sDIN EN ISO 3219 at 23°C