EBECRYL® 436

EBECRYL® 436 is a reactive chlorinated polyester resin diluted 40% with the reactive diluent trimethylolpropane triacrylate (TMPTA)(1). EBECRYL® 436 exhibits good lithographic behavior and pigment wetting properties, and fast cure response in ultraviolet light (UV) curable coatings and inks. Cured films of EBECRYL® 436 display good adhesion to metals, plastics and paper.

Principal: allnex Radcure

Chemical Family: Polyesters

End Uses: Lithographic Ink, Radiation Curable Coating, Radiation Curable Ink

Compatible Substrates & Surfaces: Metal, Paper, Plastics

Features: Excellent Adhesion, Fast Cure, Good Cure Response, Good Pigment Wetting

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Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Function
Binder
Product Code
MITM00405
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

CASE Ingredients Features
Performance Highlights

EBECRYL® 436 is characterized by:

  • Good pigment wetting
  • Good lithographic behavior
  • Fast UV cure response

UV cured products containing EBECRYL® 436 are characterized by the following performance properties:

  • Good adhesion to metals, plastics and paper

The actual properties of UV cured products also depend on the selection of other formulation components such as reactive diluents, additives and photoinitiators.

Applications & Uses

Application Method
Coating End Applications
Compatible Substrates & Surfaces
Cure Method
Ink & Toner End Applications
Markets
Applications
Product Applications

Formulated UV curable products containing EBECRYL® 436 may be applied via lithographic, screen, gravure, direct or reverse roll, and curtain coating methods.
EBECRYL® 436 is recommended for:

  • Wet lithographic inks for paper, plastics, and metals
  • Promoting adhesion for coatings on metal, plastics and paper
  • Overprint varnishes applied by lithography
  • Post-formable inks

Properties

Physical Form

Technical Details & Test Data

Typical Tack Ranges
Oligomer / Reactive diluent* Tack, g-m
EBECRYL® 436 20 - 22
EBECRYL® 436 / 5% OTA 480(*) 17 - 19
EBECRYL® 436 / 10% OTA 480 9 - 11
EBECRYL® 436 / 5% TPGDA*) 15 - 17
EBECRYL® 436 / 10% TPGDA 5 - 7

 

Note: * - 400 rpm, 90°F, 3 minutes; Thwing-Albert Electronic Inkometer

Viscosity Reduction

Graph I - EBECRYL® 436 - Viscosity reduction with reactive diluents

 

 - 1

 

Graph I shows the viscosity reduction of EBECRYL® 436 with 1,6-hexanediol diacrylate (HDDA), isobornyl acrylate (IBOA), trimethylolpropane triacrylate (TMPTA), and tripropylene glycol diacrylate (TPGDA). Although viscosity reduction can be achieved with non-reactive solvents, reactive diluents are preferred because they are essentially 100 percent converted during UV/EB exposure to form a part of the coating or ink, thus reducing solvent emissions. The specific reactive diluents used will influence performance properties such as hardness and flexibility.

 

Graph II - EBECRYL® 436 - Viscosity Vs. Temperature

 

 - 1

Graph II illustrates the change in viscosity of EBECRYL® 436 with increasing temperature.

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions
  • Care should be taken not to expose the product to high temperature conditions, direct sunlight, ignition sources, oxidizing agents, alkalis or acids.
  • This might cause uncontrollable polymerization of the product with the generation of heat. Storage and handling should be in stainless steel, amber glass, amber polyethylene or baked phenolic lined containers. Procedures that remove or displace oxygen from the material should be avoided.
  • Do not store this material under an oxygen free atmosphere. Dry air is recommended to displace material removed from the container. Wash thoroughly after handling. Keep container tightly closed. Use with adequate ventilation.

Other

Appearance
Clear liquid
Appearance (SDS)
Liquid
Color (SDS)
Yellowish
IATA/ICAO Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S.
IATA/ICAO Technical name (N.O.S.)
Trimethylolpropane triacrylate
IATA/ICAO UN Number
UN3082
IMO/IMDG Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S.
IMO/IMDG Technical name (N.O.S.)
Trimethylolpropane triacrylate
IMO/IMDG UN Number
UN3082
Item Number
Odor (SDS)
Ester
Other Hazards
Polymerization may occur from excessive heat, contamination or exposure to direct sunlight .
TDG Canada Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S.
TDG Canada Technical name (N.O.S.)
Trimethylolpropane triacrylate
TDG Canada UN Number
UN3082
USA/DOT Proper Shipping Name
Environmentally hazardous substance, liquid, N.O.S.
USA/DOT Technical name (N.O.S.)
Trimethylolpropane triacrylate
USA/DOT UN Number
UN3082
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 5.0 GardnerGardnerGardner Color Scale
Chemical Properties
ValueUnitsTest Method / Conditions
Acid Valuemax. 25.0 mg KOH/gmg KOH/g
Shelf Life & Stability
ValueUnitsTest Method / Conditions
Shelf Life0.0 dd
Mechanical Properties
ValueUnitsTest Method / Conditions
Elongation0.7 %%at break, UV cured, approx. 125μ thick films
Tensile Modulus446000.0 psipsiat break, UV cured 125 μ thick films
Tensile Strength2300.0 psipsiat break, UV cured 125 μ thick films
Physical Properties
ValueUnitsTest Method / Conditions
Density1.28 g/mLg/mLAt 25°C
Glass Transition Temperature (Tg)54.0 °C°CDynamic Mechanical Analysis (DMA) at break, UV cured 125 μ thick films
Viscosity1350.0-1650.0 cPscPsAt 60°C
Material Composition
ValueUnitsTest Method / Conditions
Oligomer Content60.0 %(W/W)%(W/W)
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Boiling Point (SDS)min. 100.0 °C°C
Density (SDS)1.28 g/cm³g/cm³
Flash Point (SDS)178.0 °C°C
Vapor Pressure (SDS)max. 0.0133 hPahPaat 20°C
Viscosity (SDS)1350.0-1650.0 mPa.smPa.sat 60°C, very highly viscous liquid