EBECRYL® 3702

EBECRYL® 3702 is a fatty acid modified bisphenol A epoxy diacrylate that exhibits outstanding flow and leveling and pigment wetting properties. Films of EBECRYL® 3702 cured by ultraviolet light (UV) or electron beam (EB) demonstrate high gloss, improved water resistance and good chemical resistance.

Principal: allnex Radcure

Chemical Family: Epoxy Acrylates

End Uses: Clearcoat, Lithographic Ink, Radiation Curable Coating, Screen Printing Ink

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Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Function
Monomer
Product Code
MITM00392
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

CASE Ingredients Features
Performance Highlights

EBECRYL® 3702 is characterized by:

  • Low odor
  • Excellent pigment wetting
  • Good flow and leveling
  • Good hydrophilic-lipophilic balance for lithography

UV/EB cured products based on EBECRYL® 3702 are characterized by the following performance properties:

  • Good chemical and water resistance
  • High gloss
  • Greater flexibility than standard bisphenol A epoxy acrylates

The final properties of UV/EB cured products also depend on the selection of other formulation components such as reactive diluents, additives and photoinitiators.

Applications & Uses

Application Method
Coating End Applications
Compatible Substrates & Surfaces
Cure Method
Ink & Toner End Applications
Markets
Applications
Product Applications

Formulated UV/EB curable products containing EBECRYL® 3702 may be applied via direct or reverse roll, offset gravure, metering rod, slot die, knife over roll, air knife, curtain, immersion and spin coating methods, as well as offset and screen printing. EBECRYL® 3702 is recommended for use in:

  • Clear coatings for paper
  • Overprint varnishes
  • Lithographic ink vehicles
  • Vehicles for metal decorating inks and clear coatings
  • Screen ink vehicles
  • Coatings for rigid and flexible plastics

Properties

Physical Form

Regulatory & Compliance

Certifications & Compliance
Contains any chemicals listed on Prop 65 (including impurities, residues, catalysts, monomers, and by-products and excluding heavy metals)?

Technical Details & Test Data

Viscosity Reduction

Graph I - EBECRYL® 3702 - viscosity reduction with reactive diluents

 - 1

Graph I shows the viscosity reduction of EBECRYL® 3702 with 1,6-hexanediol diacrylate (HDDA), isobornyl acrylate (IBOA), trimethylolpropane triacrylate (TMPTA), and tripropylene glycol diacrylate (TPGDA). Although viscosity reduction can be achieved with non-reactive solvents, reactive diluents are preferred because they are essentially 100 percent converted during UV/EB exposure to form a part of the coating or ink, thus avoiding solvent emissions. The specific reactive diluents used will influence performance properties such as hardness and flexibility.

 

Graph II - Ebecryl 3702 - viscosity vs. Temperature

 - 1

 

Graph II illustrates the change in viscosity of EBECRYL® 3702 with increasing temperature.

Packaging & Availability

Packaging Type

Principal Information

Group Principal Number
S000001
Principal

Storage & Handling

Storage Conditions
  • Care should be taken not to expose the product to high temperature conditions, direct sunlight, ignition sources, oxidizing agents, alkalis or acids. This might cause uncontrollable polymerization of the product with the generation of heat.
  • Storage and handling should be in stainless steel, amber glass, amber polyethylene or baked phenolic lined containers. Procedures that remove or displace oxygen from the material should be avoided. Do not store this material under an oxygen free atmosphere.
  • Dry air is recommended to displace material removed from the container. Wash thoroughly after handling. Keep container tightly closed. Use with adequate ventilation.

Other

Appearance
Clear liquid
Appearance (SDS)
Liquid
Color (SDS)
Green
Item Number
Odor
Low odor
Odor (SDS)
Ester like
Other Hazards
Polymerization may occur from excessive heat, contamination or exposure to direct sunlight .
USA/DOT UN Number
Not Applicable
Optical Properties
ValueUnitsTest Method / Conditions
Color Scalemax. 6.0GardnerGardner Color Scale
Chemical Properties
ValueUnitsTest Method / Conditions
Acid Valuemax. 3.0mg KOH/g
Epoxy Group Contentmax. 0.27%
Mechanical Properties
ValueUnitsTest Method / Conditions
Elongation10.0%at break, UV cured 125 μ thick films
Tensile Strength9500.0psiat break, UV cured 125 μ thick films
Physical Properties
ValueUnitsTest Method / Conditions
Density1.14g/mLAt 25°C
Glass Transition Temperature (Tg)56.0°CDynamic Mechanical Analysis (DMA) at break, UV cured 125 μ thick films
Viscosity1600.0-2800.0cPsat 65.5°C
Material Composition
ValueUnitsTest Method / Conditions
Oligomer Content100.0%(W/W)
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Autoignition Temperature (SDS)465.0°C
Boiling Point (SDS)min. 225.0°C
Density (SDS)1.14g/cm³
Glass Transition Temperature (Tg) (SDS)-9.0°C
Partition coefficient n-octanol/water (SDS)3.0-OECD 117
Vapor Pressure (SDS)max. 1.3Paat 20°C
Viscosity (SDS)1600.0-2800.0mPa.sat 65.5°C, very highly viscous liquid
Volatile Content (SDS)max. 0.5%