RHOPLEX® WL-96

RHOPLEX® WL-96 is a binder that can be used for low-VOC, brush-applied, interior clear wood finishes. It is well suited for finishing wood trim, doors, walls and floors. Finishes formulated with RHOPLEX® WL-96 or with a blend of RHOPLEX® WL-96 and a polyurethane dispersion enhance hardness, stain and chemical resistance, and other performance characteristics. Overall, the properties make a clear wood finish based on RHOPLEX® WL-96 a very viable alternative to solvent-based clear finishes.

Principal: Dow Coating Materials

Chemical Family: Chemical Mixtures & Blends

End Uses: Clearcoat, Concrete Coating, DTM Coating, Hard Coat, Metal Coating, Pigmented Coating, Primer, Sealer, Top Coat, Wood Coating, Wood Finishes

Compatible Substrates & Surfaces: Concrete, Metal, Wood

Features: Blocking Resistance, Chemical Resistance, Corrosion Resistance, Early Print Resistance, Excellent Adhesion, Excellent Flow, Fast Drying, Good Leveling, High Clarity, High Gloss, Low VOC, Mar Resistance, Stain Resistance, Water Resistance

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Enhanced TDS

Identification & Functionality

Blend
No
CASE Ingredients Functions
Chemical Family
Function
Binder
Product Code
MITM11254
Single Ingredient
Yes
Technologies
Product Families

Features & Benefits

Applications & Uses

Application Area
Application Method
Coating End Applications
Compatible Substrates & Surfaces
Markets
Applications
Formulation Information
  • Polyurethane Dispersion (PUD)
    • PUDs are used mainly to enhance wear resistance of the finish. They also depress the low shear viscosity and enhance mar resistance. Testing has shown an 80/20 (by solids) blend to provide optimum performance. For certain applications other ratios might offer a better cost/performance balance.
    • Overall, Sancure 815 dispersion, an aliphatic water-borne PUD (35% solids) has shown excellent results in combination with RHOPLEX® WL-96 Waterborne Acrylic Polymer. A satisfactory alternative would be Witcobond W-240 dispersion (30% solids).
  • Coalescents and Cosolvents
    • Coalescents play an important role in film formation of the finish under adverse conditions.
    • It is very important to choose the right type and the right level.
    • Recommended coalescents for RHOPLEX® WL-96 is Texanol ester alcohol in combination with Propasol B (Propylene glycol n-butyl ether).
    • Propasol B propylene glycol n-butyl ether is a fast evaporating coalescent which helps in shortening tack-free time. Texanol ester alcohol is a slower evaporating, water immiscible coalescent. It ensures good film formation in low-temperature/high-humidity situations.
    • Alternative coalescents would be Hexyl CARBITOL™ Solvent or DOWANOL™ Dipropylene Glycol Monobutyl Ether. Coalescents have a significant influence on the viscosity of the finish. Texanol ester alcohol tends to give higher viscosity compared to Hexyl CARBITOL™ Solvent or DOWANOL™ Dipropylene Glycol Monobutyl Ether.
    • Ethylene glycol is suggested to enhance freeze-thaw stability and wet edge properties. Propylene glycol is a satisfactory alternative.
  • Defoamers
    • We recommend the use of Patcote 519 defoamer, a silicone-type defoamer, along with mineral spirits. For optimum formulating, we suggested premixing Texanol ester alcohol, ethylene glycol, and Patcote 519 defoamer and adding them slowly to the formulation.
  • Mar Aids
    • Michem 39235 emulsion, a polyethylene wax emulsion, is recommended as the best aid to enhance mar resistance.
  • Rheology Modifiers
    • Nonionic associative rheology modifiers allow the formulator to achieve very good application properties while maintaining excellent flow and leveling. We recommend that ACRYSOL™ RM-1020 or ACRYSOL™ RM-825 Rheology Modifiers be used to get the desired rheology profiles.
  • Flatting
    • We suggest the addition of Degussa TS-100 matting agent, a flatting silica, or Syloid 169 silica to control gloss. Levels depend on the desired gloss level, e.g. 4% of Degussa TS-100 matting agent drops the 60 degree gloss by 50%.
  • pH Considerations
    • RHOPLEX® WL-96 is a self-thickening emulsion. The higher the pH of the formulation, the higher the viscosity. The recommended pH for use in wood finishes is between 7 and 8 and should be adjusted using 14% ammonia. A nonionic associative rheology modifier should be used to increase viscosity above the level achieved in the recommended pH range.
    • Also, free ammonia may cause an acceleration of yellowing in an underlying light-colored oil-based stain. The formulator should check his recommended oil-based stains in this respect.
  • Appearance
    • Clear wood finishes formulated with RHOPLEX® WL-96 enhance the warmth of the wood and exhibit good clarity over most stained substrates. When used over white or light pastel colored stains, however, the finish shows a slight yellow cast. If water-white clarity is required in a finish, RHOPLEX® WL-81 Thermoplastic Waterborne Acrylic Polymer is recommended which provides similar performance with only a minimal decrease in resistance properties.

Properties

Physical Form

Regulatory & Compliance

Certifications & Compliance
Contains any chemicals listed on Prop 65 (including impurities, residues, catalysts, monomers, and by-products and excluding heavy metals)?

Safety & Health

Safety Precautions

Dispose in accordance with all local, state (provincial) and federal regulations. Empty containers may contain hazardous residues.RHOPLEX® WL-96 and its container must be disposed in a safe and legal manner.

Packaging & Availability

Principal Information

Group Principal Number
S000005
Principal

Storage & Handling

Storage Conditions

Store RHOPLEX® WL-96 in tightly closed original containers at temperatures recommended on the product label.

Handling Information
  • Keep combustible and/or flammable products and their vapors away from heat, sparks, flames and other sources of ignition including static discharge. Processing or operating at temperatures near or above product flashpoint may pose a fire hazard. Use appropriate grounding and bonding techniques to manage static discharge hazards.
  • Failure to maintain proper volume level when using immersion heaters can expose tank and solution to excessive heat resulting in a possible combustion hazard, particularly when plastic tanks are used.

Other

Appearance
Slight yellow cast
Color (SDS)
Yellow opaque
Item Number
Odor (SDS)
Ammonia
Other Hazards
No data available
USA/DOT UN Number
Not Applicable
Chemical Properties
ValueUnitsTest Method / Conditions
pH6.5-7.5-
Mechanical Properties
ValueUnitsTest Method / Conditions
Gloss42.0-20°, white Pine Pre-stained with water-based stain, coat of stain plus 3 coats of clear, one day dry between each coat, sanding was applied between coats
Gloss43.0-20°, white Pine Pre-stained with water-based stain, coat of stain plus 3 coats of clear, one day dry between each coat, sanding was applied between coats
Gloss81.0-
Hardness32.0HVsward rocker
Hardness4.6HVtukon
Physical Properties
ValueUnitsTest Method / Conditions
Density8.62lb/galat 25°C, as dry
Density9.08lb/galat 25°C, as wet
Film Forming Temperature26.0°C
Specific Gravity1.036-
Viscosity400.0-1400.0cPsBrookfield Viscometer at 25°C
Viscosity0.6cPs
Material Composition
ValueUnitsTest Method / Conditions
Solid Content42.0%(W/W)
Application Information
ValueUnitsTest Method / Conditions
Application Temperature60.0°C
Curing Time3.0hr
SDS Physical and Chemical Properties
ValueUnitsTest Method / Conditions
Boiling Point (SDS)100.0°C
Evaporation Rate (SDS)max. 1.0%Butyl acetate = 1
Melting Point (SDS)0.0°C
Relative Vapor Density (SDS)max. 1.0-Air = 1
Specific Gravity (SDS)1.0-1.2-Water = 1
Vapor Pressure (SDS)17.0mm Hgat 20°C
Viscosity (SDS)400.0-1400.0mPa.s
Volatile Content (SDS)57.0-59.0%Water
pH (SDS)6.5-7.5-